Long-Term Photostability in Terephthalate Metal–Organic Frameworks
Dr. Diego Mateo
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorDr. Andrea Santiago-Portillo
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorDr. Josep Albero
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorDr. Sergio Navalón
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorProf. Mercedes Alvaro
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorCorresponding Author
Prof. Hermenegildo García
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorDr. Diego Mateo
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorDr. Andrea Santiago-Portillo
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorDr. Josep Albero
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorDr. Sergio Navalón
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorProf. Mercedes Alvaro
Departamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain
Search for more papers by this authorCorresponding Author
Prof. Hermenegildo García
Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 València, Spain
Search for more papers by this authorGraphical Abstract
Upon prolonged UV/Vis irradiation (weeks) terephthalate metal–organic frameworks decompose evolving CO2. The percentage of evolved CO2 depends on the structure and composition of the MOF.
Abstract
Prolonged (weeks) UV/Vis irradiation under Ar of UiO-66(Zr), UiO66 Zr-NO2, MIL101 Fe, MIL125 Ti-NH2, MIL101 Cr and MIL101 Cr(Pt) shows that these MOFs undergo photodecarboxylation of benzenedicarboxylate (BDC) linker in a significant percentage depending on the structure and composition of the material. Routine characterization techniques such as XRD, UV/Vis spectroscopy and TGA fail to detect changes in the material, although porosity and surface area change upon irradiation of powders. In contrast to BCD-containing MOFs, zeolitic imidazolate ZIF-8 does not evolve CO2 or any other gas upon irradiation.
Conflict of interest
The authors declare no conflict of interest.
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