Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility
Dr. Wenqian Chen
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorCorresponding Author
Dr. Satoshi Horike
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorDr. Daiki Umeyama
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorNaoki Ogiwara
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorTomoya Itakura
DENSO CORPORATION, 1-1 Showa-cho, Kariya, Aichi, 448–8661 Japan
Search for more papers by this authorDr. Cédric Tassel
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorYoshihiro Goto
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorProf. Hiroshi Kageyama
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorCorresponding Author
Prof. Susumu Kitagawa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606–8501 Japan
Search for more papers by this authorDr. Wenqian Chen
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorCorresponding Author
Dr. Satoshi Horike
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorDr. Daiki Umeyama
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorNaoki Ogiwara
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorTomoya Itakura
DENSO CORPORATION, 1-1 Showa-cho, Kariya, Aichi, 448–8661 Japan
Search for more papers by this authorDr. Cédric Tassel
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorYoshihiro Goto
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorProf. Hiroshi Kageyama
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Search for more papers by this authorCorresponding Author
Prof. Susumu Kitagawa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615–8510 Japan
Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606–8501 Japan
Search for more papers by this authorGraphical Abstract
Phase transitions: The glassy state of a two-dimensional (2D) Cd2+ coordination polymer crystal was prepared by a solvent-free mechanical milling process. The coordination polymer shows an increased proton conductivity and an increased dielectric constant in the glassy state (see picture).
Abstract
The glassy state of a two-dimensional (2D) Cd2+ coordination polymer crystal was prepared by a solvent-free mechanical milling process. The glassy state retains the 2D structure of the crystalline material, albeit with significant distortion, as characterized by synchrotron X-ray analyses and solid-state multinuclear NMR spectroscopy. It transforms to its original crystal structure upon heating. Thus, reversible crystal-to-glass transformation is possible using our new processes. The glass state displays superior properties compared to the crystalline state; specifically, it shows anhydrous proton conductivity and a dielectric constant two orders of magnitude greater than the crystalline material. It also shows material flexibility and transparency.
Supporting Information
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