Unraveling Inter- and Intrachain Electronics in Polythiophene Assemblies Mediated by Coordination Nanospaces
Michael W. A. MacLean
Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario, K7L 3N6 (Canada)
Search for more papers by this authorTakashi Kitao
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Search for more papers by this authorDr. Takeo Suga
Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555 (Japan)
Search for more papers by this authorProf. Dr. Motohiro Mizuno
Department of Chemistry, Graduate School of Natural Science & Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192 (Japan)
Search for more papers by this authorProf. Dr. Shu Seki
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Search for more papers by this authorCorresponding Author
Dr. Takashi Uemura
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
CREST Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)Search for more papers by this authorCorresponding Author
Prof. Susumu Kitagawa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)Search for more papers by this authorMichael W. A. MacLean
Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario, K7L 3N6 (Canada)
Search for more papers by this authorTakashi Kitao
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Search for more papers by this authorDr. Takeo Suga
Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555 (Japan)
Search for more papers by this authorProf. Dr. Motohiro Mizuno
Department of Chemistry, Graduate School of Natural Science & Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192 (Japan)
Search for more papers by this authorProf. Dr. Shu Seki
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Search for more papers by this authorCorresponding Author
Dr. Takashi Uemura
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
CREST Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)Search for more papers by this authorCorresponding Author
Prof. Susumu Kitagawa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)Search for more papers by this authorGraphical Abstract
Solitary confinement: The controlled assembly of polythiophene within the channels of a metal–organic framework was carried out. This system was used to demonstrate the assembly packing structure as a way of controlling the optical and electronic properties of the conjugated polymer.
Abstract
Strong interchain interactions render unsubstituted polythiophene un-fusible, non-melting, and insoluble. Therefore, control of the packing structure, which has a profound effect on the optical and electronic properties of the polymer, has never been achieved. Unsubstituted polythiophene was prepared in the one-dimensional channels of [La(1,3,5-benzenetrisbenzoate)]n, where polymer chains form unprecedented assembly structures mediated by the host framework. It is noteworthy that the emission and carrier transport properties were drastically changed by varying the number of chains within a particular assembly. The response of the composite to additional guests is also examined as a method to use the composites as low-concentration sensors. Our findings show that the encapsulation of polymer chains in host materials is a facile method for understanding the intrinsic properties of conjugated polymers, along with controlling and enhancing their functions.
Supporting Information
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