Hierarchical Nanosheet-Based MoS2 Nanotubes Fabricated by an Anion-Exchange Reaction of MoO3–Amine Hybrid Nanowires†
Sifei Zhuo
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
These authors contributed equally.
Search for more papers by this authorYou Xu
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
These authors contributed equally.
Search for more papers by this authorWeiwei Zhao
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Search for more papers by this authorJin Zhang
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bin Zhang
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)Search for more papers by this authorSifei Zhuo
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
These authors contributed equally.
Search for more papers by this authorYou Xu
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
These authors contributed equally.
Search for more papers by this authorWeiwei Zhao
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Search for more papers by this authorJin Zhang
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bin Zhang
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)
Department of Chemistry, School of Science, Tianjin University and The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Tianjin 300072 (China)Search for more papers by this authorThis research was supported financially by the National Natural Science Foundation of China (No. 20901057 and No. 11074185), the National Basic Research Program of China (2009CB939901), and the Innovation Foundation of Tianjin University.
Graphical Abstract
Moving onward and outward: MoO3–ethylenediamine (EDA) inorganic–organic hybrid nanowires were successfully transformed into hierarchical nanosheet-based MoS2 nanotubes (HNN-MoS2) by anion exchange with S2− anions at elevated temperature (see picture). The resulting nanotubes were highly active catalysts for photoelectrochemical hydrogen evolution by water splitting.
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