Carbon-Coated Single-Crystal LiMn2O4 Nanoparticle Clusters as Cathode Material for High-Energy and High-Power Lithium-Ion Batteries†
Sanghan Lee
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorYonghyun Cho
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorProf. Hyun-Kon Song
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorProf. Kyu Tae Lee
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorCorresponding Author
Prof. Jaephil Cho
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.comSearch for more papers by this authorSanghan Lee
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorYonghyun Cho
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorProf. Hyun-Kon Song
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorProf. Kyu Tae Lee
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Search for more papers by this authorCorresponding Author
Prof. Jaephil Cho
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.com
Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 689-798 (South Korea) http://www.jpcho.comSearch for more papers by this authorThis research was supported by the Converging Research Center Program through the Ministry of Education, Science and Technology (2012K001251).
Graphical Abstract
Electric results: The rate capability can be improved in lithium ion batteries (LIBs) by reducing the dimensions of the active material; however, the LIBs would then have insufficient electrode density. To overcome this problem, carbon-coated single-crystal LiMn2O4 nanoparticle clusters were synthesized as a cathode material for LIBs; this material can be densely packed on the current collector.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
| Filename | Description |
|---|---|
| anie_201203581_sm_miscellaneous_information.pdf1.7 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aM. Yoshio, S. Inoue, M. Hyakutake, G. Piao, H. Nakamura, J. Power Sources 1991, 34, 147–152;
- 1bR. J. Gummow, A. de Kock, M. M. Thackeray, Solid State Ionics 1994, 69, 59–67;
- 1cP. G. Bruce, B. Scrosati, J. M. Tarascon, Angew. Chem. 2008, 120, 2972–2989;
10.1002/ange.200702505 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 2930–2946;
- 1dY. Xia, Y. Zhou, M. Yoshio, J. Electrochem. Soc. 1997, 144, 2593–2600.
- 2H.-K. Song, K. T. Lee, M. G. Kim, L. F. Nazar, Adv. Funct. Mater. 2010, 20, 3818–3834.
- 3
- 3aY. Lee, M. G. Kim, J. Cho, Nano Lett. 2008, 8, 957–961;
- 3bN. Li, C. J. Patrissi, G. Che, C. R. Martin, J. Electrochem. Soc. 2000, 147, 2044–2049;
- 3cA. S. Aricò, P. Bruce, B. Scrosati, J.-M. Tarascon, W. van Schalkwijk, Nat. Mater. 2005, 4, 366–377;
- 3dY. Wang, G. Cao, Adv. Mater. 2008, 20, 2251–2269.
- 4
- 4aY. Yang, C. Xie, R. Ruffo, H. Peng, D. K. Kim, Y. Cui, Nano Lett. 2009, 9, 4109–4114;
- 4bE. Hosono, T. Kudo, I. Honma, H. Matsuda, H. Zhou, Nano Lett. 2009, 9, 1045–1051;
- 4cK. M. Shaju, P. G. Bruce, Chem. Mater. 2008, 20, 5557–5562;
- 4dY. Zhang, H.-C. Shin, J. Dong, M. Liu, Solid State Ionics 2004, 171, 25–31;
- 4eJ. Luo, L. Cheng, Y. Xia, Electrochem. Commun. 2007, 9, 1404–1409;
- 4fH. Yue, X. Huang, D. Lv, Y. Yang, Electrochim. Acta 2009, 54, 5363–5367;
- 4gS. H. Ye, J. K. Bo, C. Z. Li, J. S. Cao, Q. L. Sun, Y. L. Wang, Electrochim. Acta 2010, 55, 2972–2977;
- 4hS.-C. Park, Y.-S. Han, Y.-S. Kang, P. S. Lee, S. Ahn, H.-M. Lee, J.-Y. Lee, J. Electrochem. Soc. 2001, 148, A 680–A686;
- 4iX. Hao, O. Gourdon, B. J. Liddle, B. M. Bartlett, J. Mater. Chem. 2012, 22, 1578–1591;
- 4jB. J. Liddle, S. M. Collins, B. M. Bartlett, Energy Environ. Sci. 2010, 3, 1339–1346.
- 5
- 5aJ. Cho, J. Mater. Chem. 2008, 18, 2257–2261;
- 5bS. Lee, S. Jeong, J. Cho, ChemSusChem 2010, 3, 1260–1263.
- 6O. K. Park, Y. Cho, S. Lee, H. Yoo, H.-K. Song, J. Cho, Energy Environ. Sci. 2011, 4, 1621–1633.
- 7
- 7aY.-Y. Liang, S.-J. Bao, B.-L. He, W.-J. Zhou, H.-L. Lia, J. Electrochem. Soc. 2005, 152, A 2030–A2034;
- 7bM. Okubo, Y. Mizuno, H. Yamada, J. Kim, E. Hosono, H. Zhou, T. Kudo, I. Honma, ACS Nano 2010, 4, 741–752.
- 8J. Qian, M. Zhou, Y. Cao, X. Ai, H. Yang, J. Phys. Chem. C 2010, 114, 3477–3482.
- 9
- 9aY. J. Lee, H. Yi, W. J. Kim, K. Kang, D. S. Yun, M. S. Strano, G. Ceder, A. M. Belcher, Science 2009, 324, 1051–1055;
- 9bB. Kang, G. Ceder, Nature 2009, 458, 190–193;
- 9cH.-W. Lee, P. Muralidharan, R. Ruffo, C. M. Mari, Y. Cui, D. K. Kim, Nano Lett. 2010, 10, 3852–3856;
- 9dH. Zhang, X. Yu, P. V. Braun, Nat. Nanotechnol. 2011, 6, 277–281.
- 10US Defense Logistics Agency, Battery Performance Characteristics, http://www.mpoweruk.com/performance.htm.
- 11
- 11aJ. C. Fisher, J. Appl. Phys. 1951, 22, 74–77;
- 11bH. C. Yu, A. Van Der Ven, K. Thornton, Appl. Phys. Lett. 2008, 93, 091908;
- 11cR. E. Hoffman, D. Turnbull, J. Appl. Phys. 1951, 22, 634–639;
- 11dN. Balke, S. Jesse, A. N. Morozovska, E. Eliseev, D. W. Chung, Y. Kim, Nat. Nanotechnol. 2010, 5, 749–754.
- 12
- 12aJ. Jamnik, J. Maier, Phys. Chem. Chem. Phys. 2003, 5, 5215–5220;
- 12bN. Sata, K. Eberman, K. Eberl, J. Maier, Nature 2000, 408, 946–949;
- 12cJ. Maier, Nat. Mater. 2005, 4, 805–815.
- 13
- 13aK. Dokko, N. Nakata, K. Kanamura, J. Power Sources 2009, 189, 783–785;
- 13bK. Dokko, N. Nakata, Y. Suzuki, K. Kanamura, J. Phys. Chem. C 2010, 114, 8646–8650.
