A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C82 and a Nickel Porphyrin with High Electron Mobility†
Dr. Satoru Sato
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Hidefumi Nikawa
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shu Seki
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Lu Wang
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Search for more papers by this authorDr. Guangfu Luo
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jing Lu
State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Masayuki Haranaka
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Takahiro Tsuchiya
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shigeru Nagase
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Takeshi Akasaka
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Satoru Sato
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Hidefumi Nikawa
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shu Seki
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Lu Wang
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Search for more papers by this authorDr. Guangfu Luo
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jing Lu
State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Masayuki Haranaka
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorDr. Takahiro Tsuchiya
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shigeru Nagase
Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Takeshi Akasaka
Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Shu Seki, Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565–0871 (Japan)
Jing Lu, State Key Laboratory of Mesoscopic Physics and Department of Physics, Peking University, Beijing 100871 (P.R. China)
Shigeru Nagase, Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444–8585 (Japan)
Takeshi Akasaka, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305–8577 (Japan)
Search for more papers by this authorThis work was supported in part by a Grant-in-Aid for Scientific Research in Innovation Areas (No. 20108001, “pi-Space”), a Grant-in-Aid for Scientific Research (A) (No. 20245006), The Next Generation Super Computing Project (Nanoscience Project), Nanotechnology Support Project, Grants-in Aid for Scientific Research in Priority Areas (Nos. 20036008, 20038007) and Specially Promoted Research (No. 22000009) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. S.S. and H.N. thank the Japan Society for the Promotion of Science (JSPS) for Research Fellowships for Young Scientists. J.L. is the supported by the NSFC (Grant No. 10774003), and National 973 Projects (No. 2007CB936200, MOST of China).
Graphical Abstract
Ball and plane: The structure of La@C82 was clarified by single-crystal X-ray diffraction of samples co-crystallized with [NiII(OEP)] (OEP=octaethylporphyrin; see structure La red, N blue, Ni yellow, H pink). The charge-carrier mobility of the co-crystal was determined using flash-photolysis time-resolved microwave conductivity measurements. The material exhibited an anisotropic and high electron mobility of up to 0.9 cm2 V−1 s−1.
Supporting Information
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