Structural Evolution of “S”-Shaped [H4W22O74]12− and “§”-Shaped [H10W34O116]18− Isopolyoxotungstate Clusters†
Haralampos N. Miras Dr.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorJun Yan
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorDe-Liang Long Dr.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorLeroy Cronin Prof.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorHaralampos N. Miras Dr.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorJun Yan
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorDe-Liang Long Dr.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorLeroy Cronin Prof.
WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland (UK), Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/lee/
Search for more papers by this authorWe thank the EPSRC, WestCHEM, and the University of Glasgow for supporting this work.
Graphical Abstract
Finding the missing species: Two isopolyoxotungstate clusters with unprecedented “S”-shaped [H4W22O74]12− and “§”-shaped [H10W34O116]18− geometries are presented. The development of this structural complexity comes from the structural evolution based on the {W11} fragment and establishes a new building block principle in isopolyoxotungstate chemistry. The evolved clusters can only be isolated in the presence of sulfite ions.
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