A Self-Assembled Spin Cage
Koji Nakabayashi
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorYusuke Ozaki
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorMasaki Kawano Dr.
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorMakoto Fujita Prof. Dr.
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorKoji Nakabayashi
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorYusuke Ozaki
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorMasaki Kawano Dr.
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorMakoto Fujita Prof. Dr.
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257
Search for more papers by this authorGraphical Abstract
Going for a spin: The quantitative self-assembly of a verdazyl radical-cored ligand with [Pd(bpy)(NO3)2] (bpy=2,2′-bipyridyl) generates a large M6L4 spin cage in which multiple spin centers effectively surround the cavity. The inclusion of a radical guest within the cavity induces spin–spin interactions between the host and the guest.
Supporting Information
Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z704924_s.pdf or from the author.
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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- 14The enclathration of neutral molecules is described in the Supporting Information.
