A Nanotubular 3D Coordination Polymer Based on a 3d–4f Heterometallic Assembly†
Bin Zhao
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorPeng Cheng Prof. Dr.
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorYan Dai
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorCai Cheng
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorDai-Zheng Liao Prof.
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorShi-Ping Yan
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorZong-Hui Jiang
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorGeng-Lin Wang
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorBin Zhao
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorPeng Cheng Prof. Dr.
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorYan Dai
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorCai Cheng
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorDai-Zheng Liao Prof.
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorShi-Ping Yan
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorZong-Hui Jiang
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorGeng-Lin Wang
Department of Chemistry, Nankai University, Tianjin 300071, P.R. China, Fax: (+86) 22-2350-2458
Search for more papers by this authorThis work was supported by the National Natural Science Foundation of China (Nos. 90101028, 50173011), the NSF of Tianjin (No. 013801611) and the TRAPOYT of MOE, P.R. China
Graphical Abstract
Large pores comprising 48-membered rings characterize the isostructural lanthanide–transition-metal coordination polymers [{[Ln(dipic)3Mn1.5(H2O)3]⋅n H2O}∞], H2dipic=pyridine-2,6-dicarboxylic acid; Ln=Pr, n=2 (shown here); Ln=Gd, n=3.5; Ln=Er, n=3. Many water molecules are trapped in the nanotubular structure, and the framework remains intact on removal of the uncoordinated water molecules.
Supporting Information
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