Efficient and Selective Construction of 412 Metalla-links Using Weak C−H⋅⋅⋅Halogen Interactions
Dr. Hai-Ning Zhang
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
These authors contributed equally.
Search for more papers by this authorXi Huang
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
These authors contributed equally.
Search for more papers by this authorCorresponding Author
Prof. Dr. Guo-Xin Jin
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
Search for more papers by this authorDr. Hai-Ning Zhang
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
These authors contributed equally.
Search for more papers by this authorXi Huang
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
These authors contributed equally.
Search for more papers by this authorCorresponding Author
Prof. Dr. Guo-Xin Jin
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 2005 Songhu Rd, 200438 Shanghai, P. R. China
Search for more papers by this authorAbstract
Through a coordination-driven self-assembly method, four metalla-links and one tetranuclear monocycle were constructed with high selectivity and yield by adjusting the substituent species of the building blocks, as evidenced using X-ray crystallographic analysis, electrospray ionization-time-of-flight/mass spectrometry (ESI-TOF/MS), elemental analysis and detailed solution-state nuclear magnetic resonance (NMR) spectroscopy. Based on X-ray crystallographic analysis and independent gradient model analysis, a significant factor leading to the formation of metalla-links was the introduction of F, Cl, Br and I atoms, which generated additional weak C−H⋅⋅⋅X (X=F, Cl, Br and I) interactions. Furthermore, the dynamic conversion of metalla-links to monocyclic rings in methanol solution was systematically investigated using quantitative 1H NMR techniques.
Conflict of interests
The authors declare no conflict of interest.
Open Research
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