Proton/Electron Donors Enhancing Electrocatalytic Activity of Supported Conjugated Microporous Polymers for CO2 Reduction
Dr. Rong Wang
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
These authors contributed equally to this work.
Search for more papers by this authorXinyue Wang
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorWeijun Weng
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorYing Yao
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorDr. Pinit Kidkhunthod
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima, 30000 Thailand
Search for more papers by this authorProf. Dr. Changchun Wang
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yang Hou
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jia Guo
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorDr. Rong Wang
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
These authors contributed equally to this work.
Search for more papers by this authorXinyue Wang
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorWeijun Weng
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorYing Yao
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorDr. Pinit Kidkhunthod
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima, 30000 Thailand
Search for more papers by this authorProf. Dr. Changchun Wang
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yang Hou
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jia Guo
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438 China
Search for more papers by this authorAbstract
Metal phthalocyanines (MePc) hold great promise in electrochemical reduction of CO2 to value-added chemicals, whereas the catalytic activity of MePc-containing polymers often suffers from a limited molecular modulation strategy. Herein, we synthesize an ultrathin conjugated microporous polymer sheath around carbon nanotubes by an ionothermal copolymerization of CoPc and H2Pc via the Scholl reaction. Given the H2Pc-mediated regulation in the synthesis, CoII metal is well preserved in the form of single atoms on the polymer sheath of the carbon nanotubes. With the synergistic effect of H2Pc moieties as proton/electron donors, the composites can selectively reduce CO2 to CO with a high Faradaic efficiency (max. 97 % at −0.9 V) in broad potential windows, exceptional turnover frequency (97 592 h−1 at −0.65 V) and large current density (>200 mA cm−2). It is thus desirable to develop a family of heterogeneous polymerized MePc with molecularly regulating electrocatalytic activity.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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