Selective and Efficient Removal of Mercury from Aqueous Media with the Highly Flexible Arms of a BioMOF
Marta Mon
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorProf. Dr. Francesc Lloret
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorCorresponding Author
Dr. Jesús Ferrando-Soria
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorDr. Carlos Martí-Gastaldo
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorCorresponding Author
Dr. Donatella Armentano
Dipartimento di Chimica e Tecnologie Chimiche (CTC), Università della Calabria, 87030 Rende, Cosenza, Italy
Search for more papers by this authorCorresponding Author
Dr. Emilio Pardo
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorMarta Mon
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorProf. Dr. Francesc Lloret
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorCorresponding Author
Dr. Jesús Ferrando-Soria
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorDr. Carlos Martí-Gastaldo
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorCorresponding Author
Dr. Donatella Armentano
Dipartimento di Chimica e Tecnologie Chimiche (CTC), Università della Calabria, 87030 Rende, Cosenza, Italy
Search for more papers by this authorCorresponding Author
Dr. Emilio Pardo
Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980 València, Spain
Search for more papers by this authorAbstract
A robust and water-stable metal–organic framework (MOF), featuring hexagonal channels decorated with methionine residues (1), selectively captures toxic species such as CH3Hg+ and Hg2+ from water. 1 exhibits the largest Hg2+ uptake capacity ever reported for a MOF, decreasing the [Hg2+] and [CH3Hg+] concentrations in potable water from highly hazardous 10 ppm to the much safer values of 6 and 27 ppb, respectively. Just like with biological systems, the high-performance metal capture also involves a molecular recognition process. Both CH3Hg+ and Hg2+ are efficiently immobilized by specific conformations adopted by the flexible thioether “claws” decorating the pores of 1. This leads to very stable structural conformations reminiscent of those responsible for the biological activity of the enzyme mercury reductase (MR).
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