Die Lithium-Sauerstoff-Batterie mit etherbasierten Elektrolyten†
Dr. Stefan A. Freunberger
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorYuhui Chen
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorNicholas E. Drewett
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorDr. Laurence J. Hardwick
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorDr. Fanny Bardé
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Toyota Motor Europe, Technical Centre, Hoge Wei 33 B, 1930 Zaventem (Belgien)
Search for more papers by this authorCorresponding Author
Prof. Peter G. Bruce
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)Search for more papers by this authorDr. Stefan A. Freunberger
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorYuhui Chen
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorNicholas E. Drewett
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorDr. Laurence J. Hardwick
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Search for more papers by this authorDr. Fanny Bardé
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
Toyota Motor Europe, Technical Centre, Hoge Wei 33 B, 1930 Zaventem (Belgien)
Search for more papers by this authorCorresponding Author
Prof. Peter G. Bruce
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)
School of Chemistry, University of St Andrews, The Purdie Building, North Haugh, St Andrews KY16 9ST (Großbritannien)Search for more papers by this authorP.G.B. dankt Toyota und dem EPSRC für finanzielle Unterstützung.
Graphical Abstract
Eine der größten Hürden für weitere Fortschritte bei der nichtwässrigen Li-O2-Batterie (links im Bild) bildet der Elektrolyt. Zwar ermöglichen etherbasierte Elektrolyten beim ersten Entladen die Bildung von Li2O2, allerdings tritt, wie nun gezeigt wurde, auch eine Zersetzung auf, die mit dem wiederholten Laden und Entladen zunimmt, während die Li2O2-Bildung abnimmt, wie unter anderem durch Röntgenbeugung (Mitte) und IR-Spektroskopie (rechts) nachgewiesen wurde.
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