Proton-Induced Change of the Coordination Mode of a Boron Group: Boryl Complexes [Mn(CO)4(PR3)(BH2⋅PMe3)] and Cationic Borane σ Complexes [Mn(CO)4(PR3)(η1-BH3⋅PMe3)]+†
Takahiro Yasue Dr.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this authorYasuro Kawano Dr.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this authorMamoru Shimoi Prof.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this authorTakahiro Yasue Dr.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this authorYasuro Kawano Dr.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this authorMamoru Shimoi Prof.
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan, Fax: (+81) 3-5454-6567
Search for more papers by this author(PR3=PMe2Ph, PEt3).
Graphical Abstract
Koordinationswechsel bei Protonierung: Die Borylmangankomplexe 1 reagieren unter Protonierung zu den kationischen Boran-σ-Komplexen 2. Die Zersetzung von 2 verläuft unter heterolytischer Spaltung der Metall-koordinierten B-H-Bindung.
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