Chapter 8

Visible-Light Photocatalytic Degradation of Heavy Metal Ion Hexavalent Chromium [ Cr ( VI )]

Priya Rawat

Priya Rawat

Department of Chemistry, Amity Institute of Applied Sciences, Amity University, Sector 125, Noida, 201313, Uttar Pradesh, India

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Harshita Chawla

Harshita Chawla

Department of Chemistry, Amity Institute of Applied Sciences, Amity University, Sector 125, Noida, 201313, Uttar Pradesh, India

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Seema Garg

Seema Garg

Department of Chemistry, Amity Institute of Applied Sciences, Amity University, Sector 125, Noida, 201313, Uttar Pradesh, India

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First published: 05 August 2022

Summary

Among various toxic elements, hexavalent chromium is also found as a toxic element in water. If its concentration is too high, it can harm people's health and even lead to cancer. So, there is a need for an effective method for removal of these contaminants from water. One of the effective methods to get rid of this toxic hexavalent chromium [Cr(VI)] is to convert it into much safer form, which is trivalent chromium [Cr(III)]. This conversion can be successfully carried out by using photoreduction. This review mainly focuses on basic mechanism involving photocatalysis using titania (TiO 2 ), and its modifications with metal oxides, metal sulfide, and noble metals and also by combination with deionization technique. The results showed enhanced photocatalytic activity due to efficient separation of photogenerated charge carriers, and a decrease in bandgap leads to shifting of adsorption spectra from UV to visible region with higher stability of photocatalyst.

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