Chapter 14

Effect of MnO on Sintering and Microstructure of Al2O3-MgO-CaO Refractories

Yin Xue-liang

Yin Xue-liang

School of Materials and Metallurgy, Northeastern University, China

Liao Ning Institute of Science and Technology, China

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Lei Liu

Lei Liu

School of Materials and Metallurgy, Northeastern University, China

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Xiang Shen

Xiang Shen

School of Materials and Metallurgy, Northeastern University, China

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He Mei-le

He Mei-le

School of Materials and Metallurgy, Northeastern University, China

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Xu Lei

Xu Lei

School of Materials and Metallurgy, Northeastern University, China

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Nan Wang

Nan Wang

School of Materials and Metallurgy, Northeastern University, China

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CHEN Min

CHEN Min

School of Materials and Metallurgy, Northeastern University, China

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First published: 15 January 2016

Summary

In the current study, Al2O3-MgO-CaO refractories were prepared at 1400–1600°Cby the addition of MnO micro-powders, and the effect of MnO addition on densification behavior of the refractory was discussed. The results showed that the doped MnO dissolved to MgAl2O4 phase, and promoted the growth of MgAl2O4 grains by the formation of MgAl2O4 solid solution. As a result, the dense microstructure was obtained, with the apparent porosity decreased from 19.2% to 5.4% and the bulk density increased from 2.78g/cm3 to 3.15g/cm3 after firing at 1600°C for 2h by the addition of 4% MnO. In addition, a texture microstructure was observed, which is considered to be favorable to improve mechanical properties and the service life of Al2O3-MgO-CaO system refractories.

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