Self-Assembly of Nonionic Surfactants in Room-Temperature Ionic Liquids
Kenichi Sakai
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorTakeshi Misono
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorMasahiko Abe
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorHideki Sakai
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorKenichi Sakai
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorTakeshi Misono
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorMasahiko Abe
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorHideki Sakai
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Research Institute for Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
Search for more papers by this authorBidyut K. Paul
Search for more papers by this authorSatya P. Moulik
Search for more papers by this authorSummary
Surfactants form molecular assemblies in aqueous solutions. The assembly type strongly depends on surfactant concentration as well as temperature, thus various types of assemblies such as micelles, lyotropic liquid crystals, etc. are formed. In a manner similar to such aqueous surfactant systems, surfactants can also form molecular assemblies in room-temperature ionic liquids (RTILs). In this chapter, we focus on self-assembly of nonionic surfactants in RTILs stressing on thermodynamics of micellization of nonionic surfactants in RTILs, characterization of binary phase behaviors of nonionic surfactants with RTILs, and adsorption characteristics of nonionic surfactants at solid/RTIL interfaces. A possible future direction of studies concerning RTILs from the standpoint of colloid and interface chemistry is also addressed.
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