Volume 41, Issue 13 pp. 2371-2373

Communication

An Umpolung Approach to cis-Hyponitrite Complexes^†

Navamoney Arulsamy Dr.,

Navamoney Arulsamy Dr.

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

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D. Scott Bohle Prof. Dr.,

D. Scott Bohle Prof. Dr.

[email protected]

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

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Jerome A. Imonigie Dr.,

Jerome A. Imonigie Dr.

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

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Seth Levine,

Seth Levine

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

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Navamoney Arulsamy Dr.,

Navamoney Arulsamy Dr.

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

Search for more papers by this author

D. Scott Bohle Prof. Dr.,

D. Scott Bohle Prof. Dr.

[email protected]

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

Search for more papers by this author

Jerome A. Imonigie Dr.,

Jerome A. Imonigie Dr.

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

Search for more papers by this author

Seth Levine,

Seth Levine

Department of Chemistry University of Wyoming Laramie, WY 82071-3838 (USA) Fax: (+1) 307-766-2807

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First published: 01 July 2002

https://doi.org/10.1002/1521-3773(20020703)41:13<2371::AID-ANIE2371>3.0.CO;2-J

Citations: 68

^†

This research was supported by the National Institutes of Health, the Department of Energy, and the Air Force Office of Scientific Research.

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Graphical Abstract

Ligand formed by CN bond cleavage: Transition-metal-promoted heterolytic cleavage of the CN bond in 1 results in the formation of five new complexes of cis hyponitrite with Group 10 transition metals. The new complexes include [Ni(η²-O₂N₂)(dppf)] (dppf=1,1′-bis(diphenylphosphanyl)ferrocene) which is structurally characterized and the thermal decomposition of which follows unimolecular kinetics.

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July 3, 2002

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An Umpolung Approach to cis-Hyponitrite Complexes^†