Parallels in Cation and Anion Coordination: A New Class of Cascade Complexes†
Md. Alamgir Hossain Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorJosé M. Llinares Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorSusan Mason Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorPaula Morehouse
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorDouglas Powell Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorKristin Bowman-James Prof.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorMd. Alamgir Hossain Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorJosé M. Llinares Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorSusan Mason Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorPaula Morehouse
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorDouglas Powell Dr.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorKristin Bowman-James Prof.
Department of Chemistry University of Kansas Lawrence, KS 66045 (USA) Fax: (+1) 785-864-5396
Search for more papers by this authorThis research was sponsored by the Environmental Management Science Program, Offices of Science and Environmental Management, U.S. Department of Energy under Grant DE-FG-96ER62307.
Graphical Abstract
Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion-based cascade complex, which mimics the analogous transition-metal cascade complexes with these ligands.
Supporting Information
Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2002/z18101_s.pdf or from the author.
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
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X-ray data for 1: A crystal of dimensions 0.64×0.42×0.21 mm was selected for structural analysis. Crystal data: Mr=1161.31; triclinic space group, P
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