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Perstannylated Ammonium and Phosphonium Ions: Organometallic Onium Ions That Are also Base-Stabilized Stannylium Ions

Matthias Driess Prof. Dr.

[email protected]

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Christian Monsé Dipl.-Chem.,

Christian Monsé Dipl.-Chem.

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Klaus Merz Dr.,

Klaus Merz Dr.

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Christoph van Wüllen Priv.-Doz. Dr.,

Christoph van Wüllen Priv.-Doz. Dr.

Lehrstuhl für Theoretische Chemie der Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany)

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Matthias Driess Prof. Dr.,

Matthias Driess Prof. Dr.

[email protected]

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Christian Monsé Dipl.-Chem.,

Christian Monsé Dipl.-Chem.

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Klaus Merz Dr.,

Klaus Merz Dr.

Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49) 234-32-14378

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Christoph van Wüllen Priv.-Doz. Dr.,

Christoph van Wüllen Priv.-Doz. Dr.

Lehrstuhl für Theoretische Chemie der Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany)

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First published: 13 October 2000

https://doi.org/10.1002/1521-3773(20001016)39:20<3684::AID-ANIE3684>3.0.CO;2-U

Citations: 18

This work was supported by the Deutsche Forschungsgemeinschaft, the Ministerium für Schule, Weiterbildung und Forschung des Landes Nordrhein-Westfalen and by the Fonds der Chemischen Industrie.

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Abstract

Weakly coordinating anions and nonpolar solvents facilitate the isolation of the first NH₄⁺ and PH₄⁺ derivatives completely substituted with main group organometallic units. The triflate and BPh₄ salts of the [E(SnMe₃)₄]⁺ ions (E=N, P) undergo a rapid Me₃Sn⁺ ion exchange in THF and thus represent base-stabilized stannylium ions. The structure of the cation in [N(SnMe₃)₄]⁺[OSO₂CF₃]⁻ is depicted.

References

1 G. A. Olah, K. K. Laali, Q. Wang, G. K. S. Prakash, Onium Ions, Wiley, New York, 1998.
Google Scholar
2a E. Zeller, H. Beruda, A. Kolb, P. Bissinger, J. Riede, H. Schmidbaur, Nature 1991, 352, 141;
10.1038/352141a0
CAS Web of Science® Google Scholar
2b A. Schier, A. Grohmann, J. M. López-de-Luzuriaga, H. Schmidbaur, Inorg. Chem. 2000, 39, 547.
10.1021/ic991102x
CAS PubMed Web of Science® Google Scholar
3 M. Driess, J. Aust, K. Merz, C. van Wüllen, Angew. Chem. 1999, 111, 3967; Angew. Chem. Int. Ed. 1999, 38, 3677.
10.1002/(SICI)1521-3757(19991216)111:24<3967::AID-ANGE3967>3.0.CO;2-F
Web of Science® Google Scholar
4 The [(H₃Si)₄P]⁺ ion was reported but definitive proof of its structure has not yet been made: B. J. Aylett, H. J. Emeléus, A. G. Maddock, J. Inorg. Nucl. Chem. 1955, 1, 187.
10.1016/0022-1902(55)80055-3
CAS Web of Science® Google Scholar
5 N. Wiberg, K. H. Schmid, Z. Anorg. Allg. Chem. 1966, 345, 93;
10.1002/zaac.19663450112
CAS Web of Science® Google Scholar
U. Wannagat, Fortschr. Chem. Forsch. 1967, 9, 102;
10.1007/BFb0051671
CAS Google Scholar
Gmelin Handbuch der Anorganischen Chemie, Vol. B4, Springer, Berlin, 1989, p. 78.
Google Scholar
6 R. Bettenhausen, W. Milius, W. Schnick, Chem. Eur. J. 1997, 3, 1337.
10.1002/chem.19970030821
CAS Web of Science® Google Scholar
7a H. Huppertz, W. Schnick, Angew. Chem. 1996, 108, 2115; Angew. Chem. Int. Ed. Engl. 1996, 35, 1983;
10.1002/ange.19961081732
Web of Science® Google Scholar
7b A. Zerr, G. Miehe, G.Serghiou, M. Schwarz, E. Kroke, R. Riedel, H. Fueß, P. Kroll, R. Boehler, Nature 1999, 400, 340.
10.1038/22493
CAS Web of Science® Google Scholar
8 R. Hillwig, K. Harms, K. Dehnicke, U. Müller, Z. Anorg. Allg. Chem. 1997, 623, 676.
10.1002/zaac.199762301107
CAS Web of Science® Google Scholar
9 1: Trigonal, space group R3, a=b=10.0939(1), c=21.655(4) Å, Z=3, V=1910.7(5) Å³. 1064 independent reflections (I>2σ(I)), R1=0.0332 (observed reflections), wR2=0.0895 (all data). 2: Tetragonal, space group P4/nmm, a=b=12.4613(19), c=8.885(2) Å, Z=2, V=1379.7(4) Å³, 658 independent reflections (I>2σ(I)), R1=0.0631 (observed reflections), wR2=0.1693 (all data). Intensity data was collected with a Bruker-AXS-SMART diffractometer (Mo_Kα radiation, λ=0.71707 Å, ω-Scan, T=203 K). The structure was solved by direct methods (SHELXLS 97), the refinement against F ² was with all the measured reflections (SHELXLS 97). The non-hydrogen atoms were refined anisotropically and the H atoms isotropically. The methyl groups in the [P(SnMe₃)₄]⁺ ion of 2 are disordered, with an occupancy of 0.5, while the triflate anion is rotation disordered about a fourfold axis. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-145133 (1) and CCDC-145132 (2). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: [email protected]).
Google Scholar
10 The Sn−O bond lengths in Me₃SnOTf, which forms a polymer chain with trigonal-bipyramidal coordinated Sn atoms, are 2.34–2.37 Å: M. Driess, C. Monsé, K. Merz, unpublished results; synthesis of Me₃SnOTf:
Google Scholar
H. W. Roesky, H. Wiezer, Chem. Ber. 1971, 104, 2258.
10.1002/cber.19711040729
CAS Web of Science® Google Scholar
11 A. Appel, C. Kober, C. Neumann, H. Nöth, M. Schmidt, W. Storch, Chem. Ber. 1996, 129, 175.
10.1002/cber.19961290211
CAS Web of Science® Google Scholar
12a DFT calulations with the BP86-functional: A. B. Becke, Phys. Rev. A 1988, 38, 3098;
10.1103/PhysRevA.38.3098
CAS Web of Science® Google Scholar
J. P. Perdew, J. Chem. Phys. 1994, 100, 5829; quasi relativistic pseudo-potential at Sn with TZVP basis sets:
10.1063/1.467146
Web of Science® Google Scholar
A. Schäfer, C. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 100, 5829;
10.1063/1.467146
CAS Web of Science® Google Scholar
Program system TURBOMOLE;
Google Scholar
12b NBO analysis (same functional, same basis set) with the program suit Gaussian 98.
Google Scholar
13 D. Bongert, H. D. Hausen, W. Schwarz, G. Heckmann, H. Binder, Z. Anorg. Allg. Chem. 1996, 622, 1167, and references therein.
10.1002/zaac.19966220710
CAS Web of Science® Google Scholar
14 J. B. Lambert, B. Kuhlmann, J. Chem. Soc. Chem. Commun. 1992, 931, and references therein.
10.1039/c39920000931
CAS Web of Science® Google Scholar
15 G. A. Forsyth, D. W. H. Rankin, H. E. Robertson, J. Mol. Struct. 1990, 239, 209.
10.1016/0022-2860(90)80215-6
CAS Web of Science® Google Scholar
16 J. B. Lambert, L. Kania, S. Zhang, Chem. Rev. 1995, 95, 1191.
10.1021/cr00037a003
CAS Web of Science® Google Scholar

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Volume39, Issue20

October 16, 2000

Pages 3684-3686

Perstannylated Ammonium and Phosphonium Ions: Organometallic Onium Ions That Are also Base-Stabilized Stannylium Ions

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Perstannylated Ammonium and Phosphonium Ions: Organometallic Onium Ions That Are also Base-Stabilized Stannylium Ions

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