Structural Characterization of a Cyclohexameric meta-Phenyleneethynylene Made by Alkyne Metathesis with In Situ Catalysts
Ping-Hua Ge Dr.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorWei Fu
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorWolfgang A. Herrmann Prof.
Institut für Anorganische Chemie Technische Universität München Lichtenbergstrasse 4, 85747 Garching (Germany)
Search for more papers by this authorEberhardt Herdtweck Dr.
Institut für Anorganische Chemie Technische Universität München Lichtenbergstrasse 4, 85747 Garching (Germany)
Search for more papers by this authorCharles Campana Dr.
Bruker AXS, Inc. 5465 East Cheryl Parkway, Madison, WI 53711-5373 (USA)
Search for more papers by this authorRichard D. Adams Prof.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorUwe H. F. Bunz Prof.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorPing-Hua Ge Dr.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorWei Fu
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorWolfgang A. Herrmann Prof.
Institut für Anorganische Chemie Technische Universität München Lichtenbergstrasse 4, 85747 Garching (Germany)
Search for more papers by this authorEberhardt Herdtweck Dr.
Institut für Anorganische Chemie Technische Universität München Lichtenbergstrasse 4, 85747 Garching (Germany)
Search for more papers by this authorCharles Campana Dr.
Bruker AXS, Inc. 5465 East Cheryl Parkway, Madison, WI 53711-5373 (USA)
Search for more papers by this authorRichard D. Adams Prof.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorUwe H. F. Bunz Prof.
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax: (+1) 803-777-9521
Search for more papers by this authorU.H.F.B. and P.-H.G. thank the National Science Foundation (CHE 9814118), the Research Corporation, and the EPSCoR Office of the State of South Carolina for generous support. R.D.A. thanks the Alexander von Humboldt Foundation for an award which supported this work.
Abstract
New hexameric cyclophenyleneethynylenes (CPEs, 1) were synthesized by alkyne metathesis of meta-dipropynylated benzenes. Treatment of one of these CPE derivatives (R1=tert-butyl, hexyl, dodecyl; R2=H, methyl) with [Os3(CO)10(MeCN)2] led to a decacarbonyltriosmium–CPE complex in which the planarity of the ring was significantly disrupted, as evidenced by the results of the single-crystal X-ray diffraction analysis.
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