Volume 39, Issue 16 pp. 2922-2924

Communication

Template Synthesis of the First 1,4,7-Triphosphacyclononane Derivatives

Peter G. Edwards Prof.,

Peter G. Edwards Prof.

[email protected]

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

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Paul D. Newman Dr.,

Paul D. Newman Dr.

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

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K. M. Abdul Malik Dr.,

K. M. Abdul Malik Dr.

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

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Peter G. Edwards Prof.,

Peter G. Edwards Prof.

[email protected]

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

Search for more papers by this author

Paul D. Newman Dr.,

Paul D. Newman Dr.

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

Search for more papers by this author

K. M. Abdul Malik Dr.,

K. M. Abdul Malik Dr.

Department of Chemistry Cardiff University PO Box 912, Cardiff, CF10 3TB (UK) Fax: (+44) 29-20874083

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First published: 11 August 2000

https://doi.org/10.1002/1521-3773(20000818)39:16<2922::AID-ANIE2922>3.0.CO;2-S

Citations: 31

This work was funded by the UK Engineering and Physical Sciences Research Council.

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Abstract

The base-catalyzed cyclization of 1,2-bis(phosphanyl)ethane with trivinylphosphane on a pentamethylcyclopentadienyl iron template results in the high-yield synthesis of the first triphosphacyclononane derivative containing one vinyl-functionalized and two secondary phosphanes. The vinyl triphosphacyclononane is readily hydrogenated and alkylated to give the tritertiary 1,4,7-triethyltriphosphane macrocycle 1.

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Volume39, Issue16

August 18, 2000

Pages 2922-2924

Template Synthesis of the First 1,4,7-Triphosphacyclononane Derivatives

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Template Synthesis of the First 1,4,7-Triphosphacyclononane Derivatives

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