Synthesis, molecular and crystal structure, and properties of 10-propylthio-5,10-dihydrophenarsazine
Corresponding Author
Il'yas S. Nizamov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaSearch for more papers by this authorTat'yana P. Sorokina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAlexey V. Matseevskii
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorDmitry B. Krivolapov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAidar T. Gubaidullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIgor A. Litvinov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorBoris E. Abalonin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorElvira S. Batyeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorVladimir A. Alfonsov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorCorresponding Author
Il'yas S. Nizamov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaSearch for more papers by this authorTat'yana P. Sorokina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAlexey V. Matseevskii
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorDmitry B. Krivolapov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAidar T. Gubaidullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIgor A. Litvinov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorBoris E. Abalonin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorElvira S. Batyeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorVladimir A. Alfonsov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAbstract
10-Propylthio-5,10-dihydrophenarsazine 2 was obtained by the reaction of 10-chloro-5,10-dihydrophenarsazine 1 with propanethiol in the presence of triethylamine under mild conditions. The structure of 2 was established by X-ray single crystal diffraction. The reaction of 2 with 2,4-bis(ethylthio)-1,3,2,4-dithiadiphosphetane-2,4-disulfide 3 at room temperature affords a novel route to S-10(5,10-dihydrophenarsazine) S′-ethyl-S″-propyltetrathiophosphate 4. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:287–291, 2000
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