Abstract
The presently operating Fischer–Tropsch (FT) plants, as well as those under construction and those being planned, are summarized. As long as the price of crude oil remains above about US$50 per barrel, the FT process is economically viable. The advantages and disadvantages of the various types of FT reactors currently used are discussed. For economic reasons only, variously promoted and/or supported Co- and Fe-based catalysts are used. The many apparently different FT kinetic equations that have been published do in fact appear to be effectively similar. The various factors that control the FT product selectivity, the catalyst activity and deactivation, are temperature, gas composition, operating pressure, catalyst type, and catalyst promotion. By suitably combining the appropriate FT catalyst, FT reactor type, operating conditions, and downstream product workup processes, the amount of high quality gasoline, or diesel fuel, or linear α-alkenes can be maximized to suite the demands of the market.
Bibliography
- 1 P. Sabatier and J. B. Senderens, Compt. Rend. 134, 514 (1902).
- 2 H. H. Storch, R. B. Anderson, L. J. E. Hofer, C. O. Hawk, H. C. Anderson, and N. Golumbic, Synthetic Liquid Fuels from Hydrogenation of Carbon Monoxide, Bureau of Mines Technical Paper 709, U.S. Government Printing Office, Washington, DC, 1948.
- 3 A. N. Stranges, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, the Netherlands, Vol. 163, 2007, p. 1.
- 4 C. H. Bartholomew and R. J. Farrauto, Fundamentals of Industrial Catalytic Processes, 2nd ed., John Wiley & Sons, Inc., Hoboken, NJ, 2006.
- 5 Y. Zhang and B. Davis, Catalysis 15, 138 (2000).
- 6 J. M. Fox, Catal. Rev. Sci. Eng. 35 (2), 169 (1993).
- 7 A. P. Steynberg and M. E. Dry, eds., Studies in Surface Science and Catalysis, Elsevier, Amsterdam, the Netherlands, Vol. 152, 2004.
- 8 K. Terblanche, Hydrocarbon Eng. 2 (1997).
- 9 P. J. A. Tijm, J. M. Marriott, H. Hasenach, M. M. G. Senden, and Th. Van Herwijnen, in Proceedings of the Alternative Energy Symposium, Vancouver, Canada, May 2–4, 1995.
- 10 T. Remans, G. Jenzer, and A. Hoek, in G Ertl, H Knozinger and J. Weitkamp, eds., Handbook Heterogeneous Catalysis, Vol. 6, Wiley-VCH, Weinheim, Germany, 2008, p. 2994.
- 11 M.A. Agee, Hart's Fuel Technol. Manage. 69 (1997).
- 12 C. M. Eidt, R. F. Bauman, B. Eisenberg, J. M. Hochman, and G. C. Lahn, in Proceedings of the 14th World Petroleum Congress, Vol. 1, John Wiley & Sons, Inc., New York, 1994.
- 13 K. P. de Jong, Catal. Today 29, 171 (1996).
- 14 R. B. Anderson in P. H. Emmett, ed., Catalysis, Vol. IV, Reinhold Publishing Corp., New York, 1956, Chapts. 1–3.
- 15 A. P. Steynberg, R. L. Espinoza, B. Jager, and A. C. Vosloo, Appl. Catal. A: Gen. 186, 41 (1999).
- 16 B. Jager and R. Espinoza, Catal. Today 23, 17 (1995).
- 17 J. J. C. Geerlings, J. H. Wilson, G. J. Kramer, H. P. Kuipers, A. Hoek, and M. H. Huisman, Appl. Catal. A: Gen. 186, 27 (1999).
- 18 M. E. Dry, in D. M. Bibby, C. D. Chang, R. F. Howe, and S. Yurchak, eds., Studies in Surface Science and Catalysis, Vol. 36, Elsevier, Amsterdam, the Netherlands, 1988, p. 447.
- 19 S. T. Sie, R. Krishna, Appl. Catal. A: Gen. 186, 55 (1999).
- 20 M. E. Dry, in J. R. Anderson and M. Boudart, eds., Catalysis Science and Technology, Vol. 7, 1981, Springer-Verlag, New York, p. 593.
- 21 H. Storch, N. Golumbic, and R. B. Anderson, The Fischer–Tropsch and Related Syntheses, John Wiley & Sons, Inc., New York, 1951.
- 22 B. H. Davis, R. J. Obrien, L. G. Xu, and R. L. Spicer, Eng. Fuels 10, 921 (1996).
- 23 D. B. Bukur, L. Nowicki, R. K. Manne, and X. Lang, J. Catal. 155, 366 (1995).
- 24 D. B. Bukur, L. Nowicki, and S. A. Patel, Can. J. Chem. Eng. 74, 399 (1996).
- 25 D. B. Bukur, X. Lang, and Y. Ding, Appl. Catal. A: Gen. 186, 255 (1999).
- 26 M. E. Dry, Hydrocarbon Processes 59, 52 (1980).
- 27 M. Kraum and M. Baerns, Appl. Catal. A: Gen. 186, 189 (1999).
- 28 J. van de Loosdrecht, M. Van Der Haar, A. M. Van Der Kraan, A. J. van Dillen, and J. W. Geus, Appl. Catal. A: Gen. 150, 365 (1997).
- 29 M. K. Niemelã, A. O. I. Krause, T. Vaara, J. J. Kiviaho, and M. K. O. Rienikainen, Appl. Catal. A: Gen. 147, 325 (1996).
- 30 A. Chirinos, PhD thesis, University of Cape Town, Cape Town, South Africa, 2003.
- 31 R. Oukari, A. H. Singleton, and J. G. Goodwin, Jr., Appl. Catal. A: Gen. 186, 129 (1999).
- 32 R. C. Reuel and C. H. Bartholomew, J. Catal. 85, 78 (1984).
- 33 C. H. Bartholomew, R. B. Pannell, and J. L. Butler, J. Catal. 65, 335 (1980)
- 34 PCT/GB 99/00527 (Feb. 19, 1999), P. J. van Berge, J. van de Loosdrecht, E. A. Caricato, and G. Barradas (to Sastech).
- 35 J. van de Loosdrecht, G. Barradas, E. A. Caricato, P. J. van Berge, and J. L. Visagie, Preprints, Am. Chem. Soc., Div. Fuel Chem., 220th Meeting 587 (2000).
- 36 P. J. van Berge, S. Barradas, J. van de Loosdrecht, and J. L. Visagie, Erdöl Erdgas Kohle 117 (3), 138 (2001).
- 37 S. Bessell, Appl. Catal. A: Gen. 96, 253 (1993).
- 38 G. Calleja, A. De. Lucas, and R. van Grieken, Appl. Catal. 68, 11 (1991).
- 39U.S. Pat. 4,605,679 (Aug. 1986), T. P. Kobilinski, C. L. Kibby, R. B. Pannell, and E. L. Eddy.
- 40 E. Iglesia, S. L. Soled, R. A. Fiato, and G. H. Via, J. Catal. 143, 345 (1993).
- 41U.S. Pat. 4,804,573 (1989), S. Eri, J. G. Goodwin, G. Marcelin, and T. Riis.
- 42Eur. Pat. Appl. EP 0736326A1 (1996), R. L. Espinoza, J. L. Visagie, P. J. van Berge, and F. H. Bolder (to Sastech).
- 43 A. M. Hilmen, D. Schanke, and A. Holmen, Catal. Lett. 38, 143 (1996).
- 44 D. Schanke, A. M. Hilmen, E. Bergene, K. Kinnari, E. Rytter, E. Adnanes, and A. Holmen, Catal. Lett. 34, 269 (1995).
- 45 A. Kogelbauer, J. G. Goodwin, Jr., and R. Oukaci, J. Catal. 160, 125 (1996).
- 46 A. R. Belambe, R. Oukaci, and J. G. Goodwin, Jr., J. Catal. 166, 8 (1997).
- 47 S. Ali, B. Chen, and J. G. Goodwin, Jr., J. Catal. 157, 35 (1995).
- 48 H. Pichler, in W. G. Frankenburg, V. I. Komarewsky, and E. K. Rideal, eds., Advances in Catalysis, Vol. 4, Academic Press, Inc., New York, 1952, p. 271.
- 49 H. Schulz, in J. Falbe, ed., Chemierohstoffe aus Kohle, Thieme Verlag, Stuttgart, Germany, 1977, p. 272.
- 50 J. F. Shultz, F. S. Karn, and R. B. Anderson, U.S. Bur. Mines Rep. 6974.
- 51 M. E. Dry, Catal. Lett. 7, 241 (1990).
- 52 P. J. van Berge, R. C. Everson, in M. de Pontes, R. L. Espinoza, C. P. Nicolaides, J. H. Scholtz, and M. S. Scurrell, eds., Studies Surface Science and Catalysis, Vol. 107, Elsevier, Amsterdam, the Netherlands, 1997, p. 207.
- 53 M. K. Niemelã and A. O. I. Krause, Catal. Lett. 42, 161 (1996).
- 54 K. Takeuchi, T. Matsuzaki, H. Arakawa, T. Hanaoko, and Y. Sugi, Appl. Catal. 48, 149 (1989).
- 55 E. Iglesia, Appl. Catal. A: Gen. 161, 59 (1997).
- 56 A. Kogelbauer, J. C. Weber, and J. G. Goodwin, Jr., Catal. Lett. 34, 259 (1995).
- 57 A. M. Hilmen, D. Schanke, K. F. Hanssen, and A. Holmen, Appl. Catal. A: Gen. 186, 169 (1999).
- 58 P. J. van Berge, J. van de Loosdrecht, S. Barradas, and A. M. van der Kraan, Syngas to Fuels and Chemicals Symposium, Preprints, Am. Chem. Soc., Div. Petr. Chem. 44 (1), 84 (1999).
- 59 G. Jacobs, P. M. Patterson, Y. Zhang T. Das, J. Li, and B. H. Davis, Appl. Catal. A: Gen. 233, 215 (2002).
- 60 J. Li, G. Jacobs, T. Das, Y. Zhang, and B. H. Davis, Appl. Catal. A: Gen. 236, 67 (2002).
- 61 G. W. Huber, C. G. Guymon, T. L Conrad, B. C. Stephenson, and C. H. Bartholomew, Studies in Surface Science and Cataysis, Vol. 139, Elsevier, Amsterdam, the Netherlands, 2001, p. 423.
- 62 J. Li, G. Jacobs, T. Das, and B. H. Davis, Appl. Catal. A: Gen. 233, 255 (2002).
- 63 S. Li, S. Krishnamoorthy, A. Li, G. D. Meitzner, and E. Iglesia, J. Catal. 206, 202 (2002).
- 64 M. E. Dry, Appl. Catal. A: Gen. 138, 319 (1996).
- 65 M. E. Dry, Ind. Eng. Chem. Prod. Res. Dev. 15, 282 (1976).
- 66 R. B. Anderson, F. S. Karn, and J. F. Shultz, U.S. Bur. Mines Bull. 614 (1964).
- 67 G. A. Huff, Jr. and C. N. Satterfield, Ind. Eng. Process Des. Dev. 23, 696 (1984).
- 68 S. Ledakowicz, H. Nettelhoff, R. Kokuun, and W. D. Deckwer, Ind. Eng. Chem. Process Des. Dev. 24, 1043 (1985).
- 69 A. P. Steynberg, R. L. Espinoza, B. Jager, and A. C. Vosloo, Appl. Catal. A: Gen. 186, 41 (1999).
- 70 W. Brötz, Z. Elektrochem. 5, 301 (1949).
- 71 I. Yates and C. N. Satterfield, Energy Fuels 5, 168 (1991).
- 72 B. Sarup and B. W. Wojciechowski, Can. J. Chem. Eng. 67, 62 (1989).
- 73 T. K. Das, W. Conner, G. Jacobs, X. Zhan, J. Li, M. E. Dry, and B. H. Davis, Preprints Am. Chem. Soc. Div. Petr. Chem. 49 (2), 161 (2004).
- 74 H. Pichler, H. Schulz, and D. Kühne, Brennst. Chem. 49, 344 (1968).
- 75 I. Puskas and R. S. Hurlbut, Catal. Today 84, 99 (2003).
- 76 G. P. Van Der Laan and A. A. Beenackers, Catal. Rev. Sci. Eng. 41 (3–4), 255 (1999).
- 77 J. J. C. Geerlings, J. H. Wilson, G. J. Kramer, H. P. C. E. Kuipers, A. Hoek, and M. H. Huisman, Appl. Catal. A: Gen. 186, 27 (1999).
- 78 E. Iglesia, S. C. Reyes, R. J. Madon, and S. L. Soled, in D. D. Eley, H. Pines, and P. B. Weisz, eds., Advances in Catalysis, Vol. 39, Academic Press, Inc., New York, 1999, p. 239.
- 79 J. Patzlaff, Y. Liu, C. Graffmann, and J. Gaube, Appl. Catal. A: Gen. 186, 109 (1999).
- 80 E. W. Kuipers, I. H. Vinkenburg, and H. Oosterbeek, J. Catal. 152, 137 (1995).
- 81 H. Schulz and M. Claeys, Appl. Catal. A: Gen. 186, 7 (1999).
- 82 D. Gall, E. J. Gibson, and C. C. Hall, J. Appl. Chem. (Lond.) 2, 371 (1952).
- 83 D. Schanke, S. Vada, E. A. Blekkan, A. M. Hilmen, A. Hoff, and A. Holmen, J. Catal. 156, 85 (1995).
- 84 G. J. Haddad, B. Chen, and J. G. Goodwin, Jr., J. Catal. 161, 274 (1996).
- 85 A. Feller, M. Claeys, and E. van Steen, J. Catal. 185, 120 (1999).
- 86 M. E. Dry, T. Shingles, L. J. Boshoff, and G. J. Oosthuizen, J. Catal. 15, 190 (1969).
- 87 C. Kibby, R. Panell, and T. Kobilinsky, Preprints Am. Chem. Soc. Div. Petr. Chem 29, 1113 (1984).
- 88 F. Fischer and H. Pichler, Brennst. Chem. 20, 41 (1939).
- 89 J. Zhang, G. Jacobs, D. E. Sparks, M. E. Dry, and B. H. Davis, Catal. Today 71, 411 (2002).
- 90 M. E. Dry, Hydrocarbon Process. 61 (8) 121 (1982).
- 91 M. E. Dry, ChemSA 286 (1984).
- 92 P. Biloen and W. M. H. Sachtler, in Advances in Catalysis, Vol. 30, Academic Press, Inc., New York, 1981, p. 165.
- 93 M. E. Dry, Appl. Catal. A: Gen. 138, 319 (1996).
- 94 J. P. Hindermann, G. J. Hutchings, A. Kinnermann, Catal. Rev. Sci. Eng. 35 (1), 1 (1993).
- 95 V. Ponec, in G. Ertl, H. Knözinger, and J. Weitkamp, eds., Handbook of Heterogeneous Catalysis, Vol. 4, VCH Verlagsgesellschaft, Weinheim, Germany, 1997, p. 1876.
- 96 P. M. Maitlis, R. Quyoum, H. C. Long, and M. L. Turner, Appl. Catal. A: Gen. 186, 363 (1999).
- 97 F. Fischer and H. Tropsch, Brennst. Chem. 7, 97 (1926).
- 98 A. Steenberg and I Wender, Proc. Int. Conf. Coord. Chem. Chem. Soc. Lond. 53 (1959).
- 99 H. Pichler and H. Schulz, Chem. Ing. Tech. 42, 1162 (1970).
- 100 W. A. van Baarneveld and V. Ponec, J. Catal. 88, 382 (1984).
- 101 R. C. Brady and R. Pettit, J. Am. Chem. Soc. 103, 1287 (1981).
- 102 M. E. Dry, Catal. Today 6, 183 (1990)
- 103 B. H. Davis, Catal. Today, in press.
- 104 P. W. Schwaberg, I. S. Myburgh, J. J. Botha, P. N. Roets, and L. P. Dancuart, in Proceedings of the 11th World Clean Air Congress, Durban, South Africa, Sept. 1998.