Allyl Phenyl Sulfone
Richard K. Haynes
Hong Kong University of Science and Technology, Kowloon, Hong Kong
Search for more papers by this authorSimone C. Vonwiller
The University of Sydney, Sydney, New South Wales, Australia
Search for more papers by this authorVikas Sikervar
Arekere Mico-layout Bangalore, KA., Bangalore, India
Search for more papers by this authorRichard K. Haynes
Hong Kong University of Science and Technology, Kowloon, Hong Kong
Search for more papers by this authorSimone C. Vonwiller
The University of Sydney, Sydney, New South Wales, Australia
Search for more papers by this authorVikas Sikervar
Arekere Mico-layout Bangalore, KA., Bangalore, India
Search for more papers by this authorAbstract
[16212-05-8] C9H10O2S (MW 182.24)
InChI = 1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
InChIKey = KYPIULIVYSQNNT-UHFFFAOYSA-N
(metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent1)
Alternate Name: 1-phenylsulfonyl-2-propene.
Physical Data: bp 111–113 °C/0.5 mmHg; d 1.189 g cm−3.
Solubility: insol water; sol most organic solvents.
Form Supplied in: colorless liquid with purity >98% as obtained commercially.
Preparative Method: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure2 is most straightforward and avoids the use of strong-smelling thiols.
Purification: distillation in vacuo prior to use.
Handling, Storage, and Precautions: the sulfone is a stable compound and is handled without special precaution.
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