Synthesen und Kristallstrukturanalysen von [SbI3(SbMe3)(THF)]2 und [Li(THF)4]2[Bi2Cl8(THF)2]
Abstract
deDie Reaktion von Me3Sb mit SbI3 in Tetrahydrofuran (THF) ergibt [SbI3(SbMe3)(THF)]2 (1). [Li(THF)4]2[Bi2Cl8(THF)2] (2) wird aus LiCl und BiCl3 in Tetrahydrofuran gebildet. Die Strukturen von (1) und (2) wurden durch Röntgenbeugung am Einkristall bestimmt. Sie enthalten zentrosymmetrische Dimere mit der Geometrie kantenverknüpfter Oktaeder.
Abstract
enSyntheses and Crystal Structure Analyses of [SbI3(SbMe3)(THF)]2 and [Li(THF)4]2[Bi2Cl8(THF)2]
The reaction of Me3Sb with SbI3 in tetrahydrofuran (THF) gives [SbI3(SbMe3)(THF)]2 (1). [Li(THF)4]2[Bi2Cl8(THF)2] (2) is formed by reaction of LiCl and BiCl3 in tetrahydrofuran. The structures of (1) and (2) have been determined by X-ray diffractometry. Both structures contain centrosymmetric dimers with the geometry of edge sharing octahedra.
