Orientational growth of Al(111) caused by interposing Al3Ti layer on a highly oriented TiN(200) film
Abstract
We have investigated the preparation conditions of highly oriented TiN(200) films on Si(100) and the growth behavior of Al(111) caused by interposing Al3Ti(112) between Al and TiN(200). When TiN films are sputtered on Si(100) at 400 °C with an N2 flow ratio of 12%, stoichiometric TiN films with a single oriented (200) plane are obtained, having the same resistivity and lattice constant as the bulk material. The interposition of stoichiometric Al3Ti(112) as an interlayer makes possible the structure Al(111)/Al3Ti(112)/TiN(200)/Si(100); the reason is the small lattice mismatch at each interface. © 1998 Scripta Technica, Electron Comm Jpn Pt 2, 81(9): 46–53, 1998