Volume 67, Issue 3 pp. 473-479

Mechanical property and swelling behavior of semi-interpenetrating polymer networks based on polyvinyl alcohol and polyurethane

Qing-Ye Zhou

Corresponding Author

Qing-Ye Zhou

State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Institute of Polymer Chemistry, Department of Chemical Engineering, 66-353, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Institute of Polymer Chemistry, Department of Chemical Engineering, 66-353, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139===Search for more papers by this author
Ju Zuo

Ju Zuo

Chemistry Department, Nankai University, Tianjin 300071, People's Republic of China

Search for more papers by this author
Mou-Dao Song

Mou-Dao Song

State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Institute of Polymer Chemistry, Department of Chemical Engineering, 66-353, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

Search for more papers by this author
Bang-Hua Zhang

Bang-Hua Zhang

State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Institute of Polymer Chemistry, Department of Chemical Engineering, 66-353, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

Search for more papers by this author
Bing-Lin He

Bing-Lin He

State Key Laboratory of Functional Polymer Materials for Absorption and Separation, Institute of Polymer Chemistry, Department of Chemical Engineering, 66-353, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

Search for more papers by this author

Abstract

We have studied the mechanical property and swelling behavior of semi-interpenetrating polymer networks (semi-IPNs) of poly(vinyl alcohol) (PVA) and polyurethane (PU) with reactive groups under different experimental conditions. Tensile strength and elongation of these semi-IPNs are strongly dependent on the composition of IPNs and degree of PU crosslinking. It is clear that the composition of PVA and PU forms different IPNs morphology, which would determine the final mechanical property. The experimental results also demonstrate that the degree of crosslinking, which is controlled by heat treating temperature time, and amount of reactive groups, affects the swelling behavior of IPNs. With a change in the degree of crosslinking, the degree of swelling of IPNs is also different. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67: 473–479, 1998

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.