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Photophysical Properties of Neutral and Cationic Tetrapyridinoporphyrazines
Cristina Martí,
Santi Nonell,
Mónica Nicolau,
Tomás Torres,
Cristina Martí
Institut Químic de Sarrià, Universitat Ramon Llull, Barcelona, Spain
Search for more papers by this authorCorresponding Author
Santi Nonell
Institut Químic de Sarrià, Universitat Ramon Llull, Barcelona, Spain
*To whom correspondence should be addressed at: Institut Químic de Sarrià, Universitat Ramon Llull, Via Augusta, 390, E-08017 Barcelona (Spain); [email protected]Search for more papers by this authorMónica Nicolau
Dpto. Química Orgánica C-I. Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
Search for more papers by this authorCorresponding Author
Tomás Torres
Dpto. Química Orgánica C-I. Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
*To whom correspondence should be addressed at: Institut Químic de Sarrià, Universitat Ramon Llull, Via Augusta, 390, E-08017 Barcelona (Spain); [email protected]Search for more papers by this authorCristina Martí,
Santi Nonell,
Mónica Nicolau,
Tomás Torres,
Cristina Martí
Institut Químic de Sarrià, Universitat Ramon Llull, Barcelona, Spain
Search for more papers by this authorCorresponding Author
Santi Nonell
Institut Químic de Sarrià, Universitat Ramon Llull, Barcelona, Spain
*To whom correspondence should be addressed at: Institut Químic de Sarrià, Universitat Ramon Llull, Via Augusta, 390, E-08017 Barcelona (Spain); [email protected]Search for more papers by this authorMónica Nicolau
Dpto. Química Orgánica C-I. Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
Search for more papers by this authorCorresponding Author
Tomás Torres
Dpto. Química Orgánica C-I. Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain
*To whom correspondence should be addressed at: Institut Químic de Sarrià, Universitat Ramon Llull, Via Augusta, 390, E-08017 Barcelona (Spain); [email protected]Search for more papers by this authorFirst published: 01 May 2007
ABSTRACT
We describe the synthesis and photophysical properties of a series of neutral and cationic 3,4-tetrapyridinoporphyrazines, potential lead photosensitizers for photodynamic inactivation of bacteria. Tetracationic TPyPzs exist essentially as monomers in aqueous systems, but the presence of trialkylated compounds due to incomplete quaternization of the outer nitrogen atoms induces severe aggregation. The absorption, fluorescence, triplet, and singlet oxygen quantum yields for both the neutral and cationic compounds are comparable to those of the related phthalocyanines.
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