Using Portable Gamma-Ray Spectrometry for Testing Uranium Migration: A Case Study from the Wadi El Kareim Alkaline Volcanics, Central Eastern Desert, Egypt
Corresponding Author
Osama K. DESSOUKY
Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt
Corresponding author. E-mail: [email protected]Search for more papers by this authorHani H. ALI
Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt
Search for more papers by this authorCorresponding Author
Osama K. DESSOUKY
Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt
Corresponding author. E-mail: [email protected]Search for more papers by this authorHani H. ALI
Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt
Search for more papers by this authorAbout the first author: Osama Khairy DESSOUKY, was born at Ismailia City, Egypt. He graduated in 2002 with a B.Sc in geology from the faculty of science, Suez Canal University (Ismailia), Egypt. He received a M.Sc. (2009) and Ph.D (2013) in geology from Suez Canal University. He worked as a geologist (2003–2011) in the Egyptian Nuclear Materials Authority, assistant lecturer (2011–2013) and lecturer of geology at the Research Sector (2013 up to now). His current research is focused on the exploration of radioactive mineralization and its gneisses beside their host rocks. E-mail: [email protected]; Phone: +201003469820.
Abstract
The 300±20 Ma anomalously radioactive trachytes of Wadi El Kareim, central Eastern Desert, are a significant example of U-mineralization related to the alkaline volcanics in Egypt. Extensive portable gamma-ray spectrometric data has been utilized to identify geological factors controlling uranium mobility in the geological units along the three detailed study locations of Kab Al-Abyad, South Wadi (W) Al-Tarafawy and W. Al-Farkhah; their eTh/eU ratios averaging around 4.1, 3.7 and 5.6 respectively. Quantitative analysis with the integration of mobility maps and geological studies suggest two systems controlling U-migration within the geological units (confined system and unconfined system). In the confined system, the syngenetically formed U have experienced mobility after leaching and are redistributed in the presence of an incorporation carrier during transportation (probably as carbonate complexes). Then the retardant for uranium is achieved by sorption or by coprecipitation with the aid of Fe oxy-hydroxide, and finally the formation of immobile secondary U-bearing minerals takes place along a lithogeochemical trap. In contrast to the confined system, the unconfined one is basically lacking the lithogeochemical trap which influences the final accumulation of U-bearing minerals. The radioactivity of the trachyte rocks arises from the radioactive minerals uranophane and beta-uranophane with U- and/or Th-bearing minerals samarskite, Th-rich REE silicates, monazite and allanite.
References
- Abd El Nabi, S.H., 2013. Role of γ-ray spectrometry in detecting potassic alteration associated with Um Ba'anib granitic gneiss and metasediments, G. Meatiq area, Central Eastern Desert, Egypt. Arabian Journal of Geoscience, 6: 1249–1261.
- Adams, J.A.S., Osmond, J.K., and Rogers, J.J.W., 1959. The geochemistry of thorium and uranium. In: L.H. Ahrens (ed.), Physics and Chemistry of The Earth, 3. Pergamon, London, 299–348.
- Adams, J.A.S., Osmond, Y.K., and Rogers, J.J.W., 1969. The geochemistry of thorium and uranium, Physics and Chemistry of the earth, 3: 298–348.
10.1016/0079-1946(59)90008-4 Google Scholar
- Anderson, H., and Nash, C., 1997. Integrated lithostructural mapping of the Rossing area, Namibia using high resolution aeromagnetic, radiometric, Landsat data and aerial photographs. Exploration Geophysics, 28: 185–191.
10.1071/EG997185 Google Scholar
- Aswathanarayana, U., 1985. Principles of nuclear geology. Oxonian Press Pvt. Ltd., New Delhi, p. 397.
- Bakhit, F.S., Boutros, N.H., and El Shazly, E.M., 1989. Relation between uranium-bearing alkaline volcanic rocks and its surrounding country rocks at Abu Gazayer area. Arab journal of nuclear sciences and applications, 22–1: 113–127.
- Boyle, R.W., 1982. Geochemical prospecting for thorium and uranium deposits. Developments in economic geology, 16. Elsevier Scientific Publishing Company, Amsterdam-Oxford-New York, N.Y., ix, 498 pp.
- Brimhall, W.H. and Adams, J.A.S., 1969. Concentration changes of thorium, uranium and other metals in hydrothermally altered Conway granite, New Hampshire. Geochimica et Cosmochimica Acta, 33: 1308–1311.
- Benzing Uranium Institute, 1977. Field Gamma-Ray Spectrometric Survey No. 3, 1:292, China.
- Cambon, A.R., 1994. Uranium deposits in granitic rocks. Notes on the national training course on uranium geology and exploration. Organized by IAEA and NMA, 8 – 20 Jan. 1994, Cairo, Egypt.
- Charbonneau, B.W., Holman, P.B., and Hetu, R.J., 1997. Airborne gamma spectrometer magnetic-VLF survey of northeastern Alberta. In: MacQueen (Ed.), Exploring for Minerals in Alberta: Geological Survey of Canada Geoscience Contributions, Canada-Alberta Agreement on Mineral Development. Geological Survey of Canada Bulletin, 500: 107–1131, https://doi.org/10.4095/209209
10.4095/209209 Google Scholar
- Casas, I., Casabona, D., Duro, L., and Depablo, J., 1994. The influence of hematite on the sorption of uranium (VI) onto granite filling fractures. Chemical Geology, 113: 319–326.
- Clark, S. P. J., and Ringwood, A. E., 1964. Density distribution and constitution of the mantle. Reviews of Geophysics, 2: 35–88.
- Clark, S. P., Jr., Peterman, Z. E., and Heier, K. S., 1966. Abundances of uranium, thorium, and potassium. In:_ S.P. Clark (ed.), Handbook of Physical Constants. Geological Society of America, Memoir. 97, Sect. 24: 521–541.
- Clark, D.L., Hobart, D.E., and Neu, M.P, 1995. Actinide carbonate complexes and their importance in actinide environmental chemistry. Chemical Reviews, 95: 25–48.
- Cumberland, S. A., Douglas, G., Grice, K., and Moreau, J.W., 2016. Uranium mobility in organic matter-rich sediments: A review of geological and geochemical processes. Earth-Science Reviews 159. 160–185.
- Cuney, M., and Kyser, K., 2009. Recent and not-so-recent developments in uranium deposits and implications for exploration: Mineralogical Association of Canada, Short Course Series, Vol( 39), 257.
- Darnley, A.G., 1982. ‘Hot’ granites: some general remarks. In: Y.T. Maurice (ed.), Uranium in Granites. Geological Survey, Canada, 18–23, 1–10.
- Dawood, Y.H., Abd El-Naby, H.H., and Sharafeldin, A.A., 2004. Influence of the alteration processes on the origin of uranium and europium anomalies in trachyte, central Eastern Desert, Egypt. Journal of Geochemical Exploration, 88: 15–27.
- Dessouky, O.K., 2013. Petrology and Radioactivity of the Alkaline Volcanic Rocks along Wadi Al-Owayrishah and its surroundings, Central Eastern Desert, Egypt. Unpublished Ph.D. thesis, Facualty of science, Ismailia, Suez Canal Univeristy, Egypt, 210.
- Dessouky, O.K., 2018. Genetic link between uranium mineralization and the emplacement of limited intrusion adjacent to alkaline granites, Abu Hamr area, north Eastern Desert, Egypt. Arabian journal of Geoscience, 11: 115.
- Dessouky O.K., Dardier A.M, and Abdel Ghani I.M, 2018. Egyptian Hammamat molasse basins and their relations to arc collision stages: Implications for radioactive elements mineralization potential. Geological Journal, 1–18. https://doi.org/10.1002/gj.3220.
- Dodd, P. H., Droullard, R. F., and Lathan, C. P., 1969. Borehole logging methods for exploration and evaluation of uranium deposits. In: Mining and Groundwater Geophysics 1967, (eds.) L.W. Morley, Geological Survey of Canada, Economic Geology Report, 26: 401–415.
- El-Ghawaby, M. A., 1967. Structural and lithologic controls for localization of radioactive mineralization in South Quseir area. M. Sc. Thesis, Ain Shams University, Cairo. p. 176.
- El-Hazek, N. T., 1965. Studies on the leachability and uranium concentration of El Atshan and comparable ores in relation to the mineralogical composition. M.Sc. thesis, Ain Shams University, Cairo. p. 145.
- El-Sadek, M. A., 2009. Radiospectrometric and magnetic sig natures of a gold mine in Egypt. Journal of Applied Geophysics, 67: 34–43.
- El-Manharawy, M. S., 1972. Isotopic ages and origin of some uranium bearing volcanic rocks in Egypt. M.Sc. thesis, Cairo University, Cairo. p. 147.
- Esper S. L. and Gottfried. D., 1960. Uranium and thorium in selected suites of igneous rocks. American journal of science, Bradly volume, 258-A, 151–168.
- Fan, H., Chen, J., Wang, S., Zhao, J., Gu, D., and Meng, Y., 2017. Genesis and uranium sources of leucogranite – hosted uranium deposits in the Gaudeanmus area, central Damara Belt, Namibia: Study of element and Nd isotope geochemistry. Acta Geologica Sinica (English Edition), 91(6): 2126–2137.
- Ford, K.L., Savard, M., Dessau, J.C., Pellerin, E., Charbonneau, B.W., and Shives, R.B.K., 2001. The role of gamma ray spectrometry in radon risk evaluation: a case history from Oka, Quebec. Geoscience Canada, 28: 59–64.
- Gottfried, D., Moore, R. and Campbell, E., 1963. Thorium and uranium in some volcanic rocks from the Circum-pacific province. In: Short Papers in Geology, Hydrology, and. Topography. USGS Prof. Papers 450-E, pp. E85-E89.
- Graham, D.F., and Bonham-Carter, G.F., 1993. Airborne radiometric data: a tool for reconnaissance geological mapping using a GIS. Photogrammetric Engineering and Remote Sensing, 58: 1243–1249.
- Hassan, I. S., Dardier, A. M., Abdel ghani, I. M., Ibrahim, S. K., El-sawey, E. H. and Dessouky, O. K., 2013. Geology and radioelements potentiality of Phanerozoic trachytes of wadi Al-Owayrishah and its surroundings, central Eastern Desert, Egypt. Egyptian Journal of Geology, 57: 287–300.
- Hanson, S.L., Simons, W.B., Falster, A.U., Foord, E.E., and Lichte, F.E., 1999. Proposed nomenclature for samarskite-group minerals: new data on ishikawaite and calciosamarskite. Mineralogical Magazine. 63: 27–63
- Heier, K. S., 1963. Uranium, thorium, and potassium in eglogitic rocks. Geochimica et Cosmochimica Acta, 27: 849–860.
- Heier, K. S., and Rogers, J. J. W., 1963. Radiometric determination of thorium, uranium, and potassium in basalts and in two magmatic differentiation series. Geochimica et Cosmochimica Acta 27, 137–154.
- Heinrich, E. W., 1958. Mineralogy and geology of radioactive raw materials. McGraw Hill Book Company Inc. New York, 654.
- Hoskin, P.W.O., and Schaltegger, U., 2003. The composition of zircon and igneous and metamorphic petrogenesis. Reviews in Mineralogy and Geochemistry, 53: 25–104.
- Hussien, H. A. and EL-Kassas I. A., 1980. Some favorable host rocks for uranium and thorium mineralization in central Eastern Desert, Egypt. Proc. 5th Conf. on African Geology, Annals Geological Survey of Egypt, 10: 897–908.
- International Atomic Energy Agency, “IAEA” 1985. Technical committee meeting on uranium deposits in volcanic rocks. Vienna, Austria, International Atomic Energy Agency, Panel proceedings series; ISBN 92-0-041085-5, El Paso, TX (USA); 2–5 Apr 1984; IAEA-TC-490/1. P. 468.
- International Atomic Energy Agency “IAEA”, 2003. Guidelines for radioelement mapping using gamma ray spectrometry data-IAEA-TECDOC-1363, Vienna.
- Jaques, A.L., Wellman, P., Whitaker, A., Wyborn, D., 1997. High resolution geophysics in modern geological mapping. AGSO Journal of Australian Geology and Geophysics, 17: 159–174.
- Kamineni, D.C., Chung, C.F., Dugal, J.J.B., and Ejeckam, R.B., 1986. Distribution of uranium and thorium in core samples from the Underground Research Laboratory lease are a, southeastern Manitoba, Canada. Chemical Geology, 54: 97–111.
- Kelemen, P.B., and Matter, J., 2008. In situ carbonation of peridotite for CO2 storage: Proceedings of the National Academy of Sciences 105, 45, 17295–17300. doi:10.1073/pnas.0805794105.
- Langmuir, D., 1978. Uranium solution-Mineral Equilbria at low temperatures with applications to sedimentary ore deposits. Geochimica et Cosmochimica Acta, 42: 547–69.
- Lo, B.H. and Pitcher, D.H., 1996. A case history on the use of regional aeromagnetic and radiometric data sets for lode gold exploration in Ghana. SEG Technical Program Expanded Abstracts, 592–595. https://doi.org/10.1190/1.1826712.
10.1190/1.1826712 Google Scholar
- Locardi, E., 1977. Recent volcanoes and uranium mineralization. Proc. IAEA Vienna, Syrup. Recognition and Evaluation of Uraniferous Areas, Vienna. 1975: 229–239.
- Maurice, Y.T., 1982. Uraniferous granites and associated mineralization in the Fury and Hecla Strait Area, Baffin Island, N.W.T. In: Maurice, Y.T. (Ed.), Uranium in Granites. Geological Survey of Canada, 101–113, paper 81–23.
- McDonough, W.F., Sun, S.S., Ringwood, A.E., Jagoutz, E. and Hofmann, A.W., 1992. Potassium, Rubidium and Cesium in the Earth and Moon and the evolution of the mantle of the Earth. Geochimica et Cosmochimica Acta, 56: 1001–1012.
- Mernagh, T.P., and Miezitis, Y., 2008. A review of the geochemical processes controlling the distribution of thorium in the earth's crust and Australia's thorium resources. Geoscience Australia Record 2008/05, 48.
- Morgan, J.W., and Heier, K.S., 1966. Uranium, thorium and potassium in six U.S.G.S. standard rocks. Earth and Planetary Science Letters, 1: 158–160.
- Moxham, R.M., Foot, R.S., and Bunker, C.M., 1965. Gamma ray spectrometer studies of hydrothermally altered rocks. Economic Geology, 60: 653–671.
- Nash, J.T., 1979. Uranium and thorium in granitic rocks of northeastern Washington and northern Idaho, with comments on uranium resource potential: U.S. Geological Survey Open-File Report 39, 79–233.
- Nash, J.T., 2010. Volcanogenic uranium deposits: geology, geochemical processes, and criteria for resource assessment: U.S. Geological Survey Open-File Report, 1–99.
- Omran, A.A., and Dessouky, O.K., 2016. Ra's Abdah of the north Eastern Desert of Egypt: the role of granitic dykes in the formation of radioactive mineralization, evidenced by zircon morphology and chemistry. Acta Geochimica, 35: 368–380.
- Phair, G., and Gottfried, D., 1964. Colorado Front Range, Colorado, USA, as a uranium and thorium province. In: J.A.S. Adams, and W.M. Lowder (eds.), The Natural Radiation Environment. University of Chicago Press, Chicago, IL, 7–38.
- Robert, I.T., and Gottfried, D., 1969. Distribution of thorium, uranium, and potassium in igneous rocks of the Boulder batholith region, Montana, and its bearing on radiogenic heat production and heat flow: U.S. Geological Survey Prof: Paper 614E, 29.
- Rogers, J.J.W., 1964. Statistical tests of the homogeneity of the radioactive components of granitic rocks. In: J.A.S. Adams, and W.M. Lowder (eds.), The Natural Radiation Environment. Chicago Univ. Press, Chicago, IL, pp. 51.
- Rogers, J.J.W., and Gatlin. B., 1965. Distribution of thorium, uranium, and potassium concentrations in three cores from the Conway granite, New Hampshire, U.S.A. American Journal of Science, 263: 817–822.
- Rogers, J.J.W., and Adams, J.A.S., 1969. Uranium and thorium, In: K. H. Wedepohl (ed.), Handbook of geochemistry. Berlin, Springer-Verlag, Vol. 11 3, 92-B-1 to 92-0-8 and 90-Bb-1 to 90-00-5, 201.
- Rudnick, R.L., and Fountain, D.M., 1995. Nature and composition of the continental crust: a lower crustal perspective. Reviews of Geophysics, 33: 267–309.
- Salman, A.B., 1968. Geology of radioactive occurrences in El Kareim-El Owersha area, Central Eastern Desert, Egypt. M.Sc. thesis, Ain Shams University, Cairo. P.159.
- Sanderson, D.C.W., Allyson, J.D., Tyler, A.N., and Scott, E.M., 1995. Environmental Applications of Airborne Gamma Ray Spectrometry, Application of Uranium Exploration Data and Techniques in Environmental Studies, IAEA-TECDOC-827. IAEA, Vienna 71–79.
- Sikka, D.B., 1962. Aero-gamma ray spectrometer aids in the detection of faults. Research Bulletin of the Panjab University. Vol. 13, Parts l-ll, 91–102.
- Smith, D.K., Gruner, J.W., and Lipscomb, W.M., 1957. The crystal structure of uranophane. American Mineralogist, 42: 594–618.
- Stuckless, J.S., Bunker, C.M., Bush, C.A., Doering, W.P., and Scott, J.H., 1977. Geochemical and petrologic studies at a uraniferous granite from the Granite Mountains, Wyoming. U.S. Geological Survey Journal of Research, 5: 61–81.
- Stuckless, J.S., and Nkomo, I.T., 1978. Uranium-lead isotope systematics in uraniferous alkali-rich granites from the Granite Mountains, Wyoming, in Implications for uranium source rocks. Economic Geology, 73: 427–441.
- Stuckless, J.S., and Ferreira, C.P., 1976. Labile uranium in granitic rocks. In: International symposium on exploration of uranium ore deposits: Proc. Symposium, Vienna, International Atomic Energy Agency, ISBN 92-0-040076-0, p. 717–730p. 717–730.
- Tawfik, S.Z., 2010. Geochemistry and Radioactivity of El Atshan–Wadi Kareem Phanerozoic Volcanics, central Eastern Desert, Egypt. Ph.D thesis, Alexandria University.
- Taylor, S.R., 1964. Abundance of chemical elements in the continental crust; a new table. Geochimica et Cosmochimica Acta, 28: 1273–1285.
- Turekian, K.K., and Wedepohl, K.H., 1961. Distribution of Elements in Some Major Units of Earth's Crust. Geological Society of America Bulletin, 72: 175–190.
- Vinogradov, A.P., 1962. Average contents of chemical elements and major types of igneous rocks in the Earth's crust. Geokhimiya, 7: 555–571.
- Wenrich, K.J., 1985. Geochemical characteristics of uranium-enriched volcanic rocks. IAEA-TC-490/1. 29–51.