Geochemical Stream Sediment Survey in the Wadi Umm Rilan Area, South Eastern Desert, Egypt: A New Occurrence for Gold Mineralization
Corresponding Author
Mohamed Abdallah Gad DARWISH
Geology Department, Faculty of Science, Aswan University, Egypt
Corresponding author. E-mail: [email protected]Search for more papers by this authorCorresponding Author
Mohamed Abdallah Gad DARWISH
Geology Department, Faculty of Science, Aswan University, Egypt
Corresponding author. E-mail: [email protected]Search for more papers by this authorAbout the first author:
Mohamed Abdallah Gad Darwish, was born in 1965 in Aswan, Egypt. He graduated as geologist 1987, from Aswan Faculty of Science, Assiut University. He received B.Sc. in Geology (1987) from Assiut University, M. Sc. Economic geology (1996) and Ph. D. Economic geology (2004) from South Valley University, with two Theses on geochemical exploration. He worked as Demonstrator (1990–1996), Assistant Lecturer (1996–2003) and Lecturer (2004–2012) of Economic geology and geochemical exploration at South Valley University, and Associate Professor (2012 up to now) of Economic geology and geochemical exploration at Aswan University. His current research studies are on the geochemical exploration, SEM for gold and ore minerals, mines evaluation and environmental assessments.
Abstract
The present paper investigates the stream sediment geochemistry, behavior of gold and associated elements, delineates Au-anomalous sites and defines related sources in the Wadi Umm Rilan area. Fifty three major and trace elements were analyzed using ICP-MS and treated applying various statistical and mapping techniques. The results showed a significant difference of mean and median Au and most chemical elements in the three portions of the area, and higher values were recorded in the western portion. Furthermore, Au-anomalous sites appeared in upper and lower parts of the Wadi Umm Rilan, along the tributaries of metavolcanic unit and near granitoid contacts. This indicates the main source of Au mineralization is related to emplacement of granitoid plutons and accompanying hydrothermal solutions. There are significant indications for the presence of more than one mineralization event forming a probable single major episode of mineralization in the area, involving Au, Pb and U mineralizations. Geology, geomorphologic aspects and weathering processes could control stream sediment geochemistry, anomalies of Au and associated elements, elemental association and their dispersion patterns. Therefore, the area is fruitful and regarded as a promising target for Au exploration, using Ag, As, Sb, Cd, Cs, and Tl as pathfinder elements.
References
- Aitchison, J., 1983. Principal component analysis of compositional data. Biometrika, 70: 57–65.
- Aitchison, J., 1986. The Statistical Analysis of Compositional Data. London: Chapman and Hall.
10.1007/978-94-009-4109-0 Google Scholar
- Asami, M., Suzuki, K., and Grew, E.S., 2002. Chemical Th–U–total Pb dating by electron microprobe analysis of monazite, xenotime and zircon from the Archean Napier Complex, East Antarctica: evidence for ultra-high-temperature metamorphism at 2400 Ma. Precambrian Research, 114 (3–4): 249–275.
- Atsuyuki, O., Noboru, I., Shigeru, T., and Yoshiko, T., 2005. Influence of surface geology and mineral deposits on the spatial distributions of element concentrations in the stream sediments of Hokkaido Japan. Journal of Geochemical Exploration, 86: 86–103.
- Bhuiyan, M.A.H., Rahman, M.J.J., Dampare, S.B., and Suzuki, S., 2011. Provenance, tectonics and source weathering of modern fluvial sediments of the Brahmaputra–Jamuna River, Bangladesh: Inference from geochemistry. Journal of Geochemical Exploration, 111: 113–137.
- Boyle, R.W., 1979. The geochemistry of gold and its deposits. Geological Survey of Canada Bulletin, 280: 583.
- Chandrajith, R., Dissanayakeb, C.B., and Tobschall, H.J., 2001. Application of multi-element relationships in stream sediments to mineral exploration: a case study of Walawe Ganga Basin, Sri Lanka. Applied Geochemistry, 16: 339–350
- Cloke, P.L., and Kelly, W.C., 1964. Solubility of gold under inorganic supergene conditions. Economic Geology, 59: 259–270.
- Cocker, M.D., 1996. Background stream sediment geochemistry and hydrogeochemistry of a major river basin in Georgia: use in industrial mineral resource evaluation and environmental studies. In: G.S. Austin, G.K. Hoffmann, J. Baker, J. Zidek, N. Gilson (eds.), Proceedings of the 31st Forum on the Geology of the Industrial Minerals—The Borderland Forum. N.M. Bur. Min. Miner. Resour. Bull., 154: 197–206.
- Darnley, A.G., 1990. International geochemical mapping: a new global project. In: A.G. Darnley, and A.G. Garrett (eds.), International Geochemical Mapping. Journal of Geochemical Exploration, 39: 1–14.
- Darwish, M.A.G., and Poellmann, H., 2008. Geochemical stream sediment survey for gold in Wadi Allaqi-Wadi Haimur area, South Egypt. Journal of Sedimentological Society of Egypt, 16: 37–50.
- Darwish, M.A.G., and Poellmann, H., 2010. Geochemical exploration for gold in the Nile Valley Block (A) area, Wadi Allaqi, south Egypt. Chemie der Erde, 70: 353–362.
- Ding, C., Dai, P., Bagas, L., Nie, F., Jiang, S., Wei, J., Ding, C., Zuo, P., and Zhang, K., 2016. Geochemistry and Sr–Nd–Pb isotopes of the granites from the Hashita Mo deposit of Inner Mongolia, China: Constaints on their origin and tectonic setting. Acta Geologica Sinica (English Edition), 90 (1): 106–120.
- Eby, G.N., 1990. The A-type granitoids: a review of their occurrence and chemical characteristics and speculations on their petrogenesis. Lithos, 26: 115–134.
- Egyptian Geological Survey and Mining Authority (EGSMA), 1996. Geologic map of Wadi Jabjabah quadrangle, Egypt. Geological Survey, Cairo, Egypt.
- EL Kazzaz, Y.A., and Taylor, E.W.G., 1996. Tectonic-stratigraphy of Neoproterozoic in Wadi Allaqi, South Eastern Desert, Egypt. In: Proceeding Egypt Geological Survey. Centennial Conf. (1896–1996), Cairo, Special Publication Paper. 75: 225–262.
- EL Kazzaz, Y.A., 1998. Tectonic setting of granite intrusions in the Central Wadi Allaqi, South Eastern Desert, Egypt. Annual Geological Survey Egypt, Cairo, Egypt. 21: 385–394.
- EL Kazzaz, Y.A.H.A., and Taylor, W.E.G., 2001. Tectonic evolution of the Allaqi shear zone and implications for Pan-African terrane amalgamation in the south Eastern Desert, Egypt. Journal of African Earth Sciences, 33 (2): 177–197.
- ElNemr, A.H., ElSikaily, A., and Khaled, A., 2007. Total and leachable heavy metals in muddy and sandy sediments of Egyptian coast along Mediterranean Sea. Estuarine. Coastal and Shelf Science, 129: 151–168.
- Ezz-El-Din, N.A.M., 2002. Mineralogical and geochemical studies on the sulphides and gold mineraliztion at Wadi Umm Rilan El Atshan, Sout Eastern Desert Egypt. (M.Sc. Fac. Sci.) Al Azhar University, Cairo, Egypt. 178.
- Filzmoser, P., Hron, K., and Reimann, C., 2009. Principal components analysis for compositional data with outliers. Environmetrics, 20: 621–632.
- Fletcher, W.K., 1997. Stream sediment geochemistry in today's exploration world. In: A. GubinsG. (ed.), Proceedings of Exploration '97—4th Decennial International Conference on Mineral Exploration, 249–260
- Fowler, J., Cohen, L., and Jarvis, P., 1998. Practical Statistics for Field Biology. Chichester: John Wiley & Sons. 259.
- Gao, Z.L., and Kwak T.A.P., 1997. The geochemistry of wall rock alteration in turbidite-hosted gold vein deposits, central Victoria, Australia. Journal of Geochemical Exploration, 59: 259–274.
- Guillén, M.T., Delgado, J., Albanese, S., Nieto, J. M., Lima, A., and De Vivo, B., 2011. Environmental geochemical mapping of Huelva municipality soils (SW Spain) as a tool to determine background and baseline values. Journal of Geochemical Exploration, 109: 59–69.
- Guillén, M. T., Delgado, J., Albanese, S., Nieto, J. M., Lima, A., and De Vivo, B., 2012. Heavy metals fractionation and multivariate statistical techniques to evaluate the environmental risk in soils of Huelva Township (SW Iberian Peninsula). Journal of Geochemical Exploration, 119–120: 32–43.
- Halamic, J., Peh, Z., Bukovec, D., Miko, S., and Galovic, L., 2001. A factor model of the rela-tionship between stream sediment geochemistry and adjacent drainage basinlithology, Medvednica Mt., Croatia. Geology Croat. 54 (1): 37–51.
- Hale, M., and Plant, J.A., 1994. Drainage geochemistry. In: G.J.S. Govett (ed.), Handbook of Exploration Geochemistry. Elsevier, Amsterdam, v6.
- Hamilton, T.W., Ellis, J., Florence, T.M., and Fardy, J.J., 1983. Analysis of gold in surface waters from Australian gold fields: an investigation into direct hydrogeochemical prospecting for gold. Economic Geology, 78: 1335–1341.
- Hao, L., Zhao, X., Zhao, Y., Lu, J., and Sun, L., 2014. Determination of the geochemical background and anomalies in areas with variable lithologies. Journal of Geochemical Exploration, 139: 177–182.
- Hawkes, H.E., and Webb, J.S., 1962. Geochemistry in Mineral Exploration. New York: Harper and Row, NY.
- Hine, I.S., Chappell, B.W., and White, J.R., 1978. Contrasts between I- and S-type granitoids of the Kosciusko batholith. Journal Geological Society Australia, 25: 219–234.
- Hoaglin, D., Mosteller, F., and Tukey, J., 2000. Understanding robust and exploratory data analysis ( 2nd edition). New York: Wiley & Sons.
- Hosny, H.H., Sharaf El-Din, S.M., and Abu-Zeid, A.T., 2002. Tectonic framework of the basement rocks of Umm Shilman area, Southeast of Aswan delineated from aeromagnetic data. Al Azhar Bull. Sci., Fac. Sci. Al Azhar University, Cairo, Egypt. 13 (2): 139–169.
- Hussein, A.A.A., Ali, M.M., and El-Ramly, M.F., 1982. A proposed new classification of the granites of Egypt. Journal Volcanology Geothermal Research, 14: 187–198.
- Jordan, C., Zhang, C., and Higgins, A., 2007. Using GIS and statistics to study influences of geology on probability features of surface soil geochemistry in Northern Ireland. Journal of Geochemical Exploration, 93: 135–152.
- Kaiser, H.F., 1958. The varimax criterion for analytic rotation in factor analysis. Psychometrika, 23: 187–200.
- Kusky, T.M., and Ramadan, T.M., 2002. Structural controls on Neoproterozoic mineralization in the South Eastern Desert, Egypt: an integrated field, Landsat TM, and SIR-C/X SAR approach. Journal of African Earth Sciences 35: 107–121.
- Lahermo, P., Väänänen, P., Tavainen, T., and Salminen, R., 1996. Geochemical Atlas of Finland: Part 3. Environmental Geochemistry–Stream Waters and Sediments. Geological Survey of Finland, Espoo.
- Lapworth, D. J., Knights, K. V, Key, R. M., Johnson, C. C., Ayoade, E., Adekanmi, M. A., Arisekola, T. M., Okunlola, O. A., Backman, B., Eklund, M., Everett, P. A., Lister, R. T., Ridgway, J., Watts, M. J., Kemp, S. J., and Pitfield, P. E.J., 2012. Geochemical mapping using stream sediments in west-central Nigeria: Implications for environmental studies and mineral exploration in West Africa. Applied Geochemistry, 27: 1035–1052.
- Mason, R.A., 1987. Ion microprobe analysis of trace elements in calcite with an application to the cathodoluminescence zonation of limestone cements from the Lower Carboniferous of South Wales, U.K. Chemical Geology, 64 (3–4): 209–224.
- Maynard, J.B., 1983. Geochemistry of sedimentary ore deposits. New York: Springer-Verlag.
10.1007/978-1-4613-9493-8 Google Scholar
- Moreno, T., Querol, X., Castillo, S., Alastuey, A., Cuevas, E., Herrmann, L., Mounkaila, M., Elvira, J., and Gibbons, W., 2006. Geochemical variations in aeolian mineral particles from the Sahara–Sahel Dust Corridor. Chemosphere, 65 (2): 261–270
- Nie, F., Dong, G., Mo, X., Wang, X., Fan, W., Dong, M., and Zhu, H., 2014. Petrogenesis of Kejie granite in the northern changing-Menglian zone, western Yunnan: Constraints fron zircon U–Pb geochronology, geochemistry and Hf isotope. Acta Geologica Sinica (English Edition), 88 (3): 754–765.
- Niu, X., Yang, J., Liu, F., Feng, G., Tian, Y., Zhang, L., Gao, J., and Zhao, Y., 2015. Mineralogical and geochemical constraints on origin of the ultramafic rocks from Wuwamen ophiolite at he southern margin of middle Tiangshan, Xinjiang. Acta Geologica Sinica (English Edition), 89 (2): 70–71.
- Owens, P.N., Batalla, R.J., Collins, A.J., Gomez, B., Hicks, D.M., Horowitz, A.J., Kondolf, G.M., Marden, M., Page, M.J., Peacock, D.H., Petticrew, E.L., Salomons, W., and Trustrum, N.A., 2005. Fine-grained sediment in rivers systems: environmental significance and management issues. River Res. Appl. (Fully spelt). 21: 693–717.
- Papadopoulou-Vrynioti, K., Alexakis, D., Bathrellos, G. D., Skilodimou, H. D., Vryniotis, D., Vassiliades, E. and Gamvroula, D., 2013 Distribution of trace elements in stream sediments of Arta plain (western Hellas): The influence of geomorphological parameters. Journal of Geochemical Exploration, 134: 17–26.
- Pazand, K., Hezarkhani, A., Ataei, M., and Ghanbari, Y., 2011. Application of multifractal modeling technique in systematic geochemical stream sediment survey to identify copper anomalies: A case study from Ahar, Azarbaijan, Northwest Iran. Chemie der Erde, 71: 397–402.
- Perumala, R.V.S. and Merkle, R.K.W. 2014. Hydrothermal Högbomite associated with vanadiferous–titaniferous (V–Ti) bearing magnetite bands in Bhakatarhali chromite mine, Nuggihali greenstone belt, western Dharwar craton, Karnataka, India. Acta Geologica Sinica (English Edition), 88 (3): 845–853.
- Petersen, L.W., Moldrup, P., Jacobsen, O.H., and Rolston, D.E., 1996. Relations between specific surface area and soil physical and chemical properties. Soil Scicense, 161: 9–21.
- Pohl, J.R., and Emmermann, R., 1991. Chemical composition of the Sri Lankan Precambrian basements. Crystalline Crust of Sri Lanka (Part 1), Professional Paper No. 5. Geological Survey and Mines Bureau, Sri Lanka.
- Ramadan, T.M., Abdelsalam, M.J., and Stern, R.J., 1999. Mineral exploration with Landsat TM and SIR-C/X SAR images: Wadi Allaqi Suture, South Eastern Desert, Egypt. South-Central Geol. Soc. Amer. Meeting, 1, Lubbock, Texas, A33.
- Ramadan, T.M., Abdelsalam, M.G., and Stem, R.J., 2001. Mapping gold bearing massive sulfide deposits in the Neoproterozoic allaqi suture, Southeast Egypt with Landsat TM and SIR = C/X SAR images. Photogramm Eng Remote Sensing, 67 (4): 491–497.
- Ranasinghe, P.N., Fernando, G.W.A.R, Dissanayake, C.B., Rupasinghe, M.S., and Witter, D.L., 2009. Statistical evaluation of stream sediment geochemistry in interpreting the river catchment of high-grade metamorphic terrains. Journal of Geochemical Exploration, 103: 97–114.
- Rantitsch, G., 2000. Application of fuzzy clusters to quantify lithological background concentrations in stream-sediment geochemistry. Journal of Geochemical Exploration, 71: 73–82.
- Rantitsch, G., 2004. Geochemical exploration in a mountainous area by statistical modeling of polypopulational data distributions. Journal of Geochemical Exploration, 82: 79–95.
- Rao, W., Tan, H., Jiang, S., and Chen, J., 2011. Trace element and REE geochemistry of fine-andcoarse-grained sands in the Ordos deserts and links with sediments in surrounding areas. Chemie der Erde, 71 (2): 155–170.
- Rashwan, A.A., Taylor, W.E., and El-Kazzaz, Y.A., 1993. Geological and structural evolution of Wadi Umm Rilan area southeastern Desert, Egypt. 30 Years Inter. Co-oper. On Geol Egypt and relat. Sci., Cairo, Egypt. Abstract, 30–31.
- Reedman, J.H., 1979. Techniques in Mineral Exploration. Applied Science Publishers.
10.1007/978-94-009-9227-6 Google Scholar
- Reimann, C., Filzmoser, P., and Garrett, R.G., 2005. Background and threshold: critical comparison of methods of determination. Science Total Environment, 346: 1–16.
- Reimann, C., Filzmoser, P., Fabian, K., Hron, K., Birke, M., Demetriades, A., Dinelli, E., Ladenberger, A., and the GEMAS Project Team, 2012. The concept of compositional data analysis in practice—total major element concentrations in agricultural and grazing land soils of Europe. Science Total Environment, 426: 196–210.
- Rose, A.W., Dahlberg, E.C., and Keith, M.L., 1970. Multiple regression technique for adjusting background values in stream sediment geochemistry. Economic Geology, 6: 156–165.
10.2113/gsecongeo.65.2.156 Google Scholar
- Sadeghi, M., Petrosino, P., Ladenberger, A., Albanese, S., Andersson, M., Morris, G., Lima, A., De Vivo, B., and The GEMAS Project Team, 2013. Ce, La and Y concentrations in agricultural and grazing-land soils of Europe. Journal of Geochemical Exploration, 133: 202–213.
- Šajn, R., Aliu, M., Stafilov, T., and Alijagić, J., 2013. Heavy metal contamination of topsoil around a lead and zinc smelter in Kosovska Mitrovica/Mitrovicë, Kosovo/Kosovë. Journal of Geochemical Exploration, 134: 1–16.
- Schwertman, N.C., and Silva, D.R., 2007. Identifying outliers with sequential fences. Computational Statistics & Data Analysis, 51 (8): 3800–3810.
- Stanley, C.R., and Sinclair, A.J., 1989. Comparison of probability plots and gap statistics in the selection of threshold for exploration geochemistry data. Journal of Geochemical Exploration, 32: 355–357.
- Suh, C.E., Dada, S.S., and Matheis, G., 2000. Host rock geology and geochemistry of the Zona uranium occurrence, Peta Gulf Syncline (Upper Benue Trough), northeast Nigeria. Journal of African Earth Science, 31: 619–632.
- Tam, N.F.Y., and Wong, Y.S., 2000. Spatial variation of heavy metals in surface sediments of Hong Kong mangrove swamps. Environmental Pollution, 110: 195–205.
- Taylor, W.E.G., El Hamad, Y.A., El-Kazzaz, Y.A., and Rashwan, A.A., 1993. An outline of the tectonic framework for the Pan-African orogeny in the vicinity of Wadi Um Relan, SE Desert, Egypt. In: U. Thorweihe, and H. Shandelmeier (eds.), Geoscientific Research in NE Africa. Balkema, Rotterdam, 31–34.
- Tukey, J.W., 1997. Exploratory Data Analysis. Addison-Wesley Publishing Company, Massachusett, Reading.
- Verma, S., Guevara, M., and Agrawal, S., 2006. Discriminating four tectonic settings: five new geochemical diagrams for basic and ultrabasic volcanic rocks based on log-ratio transformation of major-element data. Jouranl of Earth Systmatic Science, 115: 485–528.
- Wang, K., Wang, Z., Zhang, Y., and Wang, G., 2015. Geochronology and geochemistry of mafic rocks in Xuhe Shaanxi, China: Implications for petrogenesis and mantle dynamics. Acta Geologica Sinica (English Edition), 89 (1): 187–202.
- Webster, J.G., and Mann, A.W., 1984. The influence of climate, geomorphology and primary geology on the supergene migration of gold and silver. Journal of Geochemical Exploration, 22: 21–42.
- Yousefi, M., Kamkar-Rouhani, A., and Carranza, E. J. M., 2012. Geochemical mineralization probability index (GMPI): A new approach to generate enhanced stream sediment geochemical evidential map for increasing probability of success in mineral potential mapping. Journal of Geochemical Exploration, 115: 24–35
- Zhang, C., and Wang, L., 2001. Multi element geochemistry of sediments from Pearl River System, China. Applied Geochemistry, 16: 1251–1259.
- Zhang, Z., Cheng, Q., Yao, L., Bai, H., and Li, C., 2016. Zircon U–Pb–Hf isotopes systematic and geochemistry of the granites in the Wurinitu molybdenum deposit, Inner Mongolia, China: Implications for tectonic setting and genetic types of mineralization. Acta Geologica Sinica (English Edition), 90 (6): 2066–2079.