Volume 70, Issue 6 pp. 650-655

Icosahedral symmetry breaking: C60 to C78, C96 and to related nanotubes

First published: 16 October 2014
Marzena Szajewska, e-mail: [email protected]

Abstract

Exact icosahedral symmetry of C60 is viewed as the union of 12 orbits of the symmetric subgroup of order 6 of the icosahedral group of order 120. Here, this subgroup is denoted by A2 because it is isomorphic to the Weyl group of the simple Lie algebra A2. Eight of the A2 orbits are hexagons and four are triangles. Only two of the hexagons appear as part of the C60 surface shell. The orbits form a stack of parallel layers centered on the axis of C60 passing through the centers of two opposite hexagons on the surface of C60. By inserting into the middle of the stack two A2 orbits of six points each and two A2 orbits of three points each, one can match the structure of C78. Repeating the insertion, one gets C96; multiple such insertions generate nanotubes of any desired length. Five different polytopes with 78 carbon-like vertices are described; only two of them can be augmented to nanotubes.

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