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New insights into structural diversity of open-framework silicates inspired by the exploration of the Cs2O–CaO–SiO2 system

Sergey M. Aksenov

Corresponding Author

Sergey M. Aksenov

Kola Science Centre, Russian Academy of Sciences, Laboratory of Arctic Mineralogy and Material Sciences, 14 Fersman str., Apatity, 184209 Russian Federation

Kola Science Centre, Russian Academy of Sciences, Geological Institute, 14 Fersman str., Apatity, 184209 Russian Federation

Sergey M. Aksenov, e-mail: [email protected]Search for more papers by this author
First published: 07 July 2025

Abstract

The structure of unique compound Cs4Ca[Si8O19] reported recently by Kahlenberg [(2025), Acta Cryst. B81, 325–336] contributes to the broader understanding of structure–property relationships in open-framework silicates (as well as silicates with mixed octahedral–tetrahedral frameworks), with potential implications for ion-exchange, catalysis, and materials with tailored thermal expansion.

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