catena-Poly[[bis(α-thenoyltrifluoroacetonato-κ2O,O′)copper(II)]-μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene-κ2N:N′]
First published: 13 February 2007
Hans-Conrad zur Loye, e-mail: [email protected]
Abstract
The title compound, [Cu(C8H4F3O2S)2(C12H10N4)]n or [Cu(tta)2(L2)2]n (L2 = 1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene and tta = α-thenoyltrifluoroacetonate), consists of undulating chains containing two crystallographically distinct CuII centers that are each located on inversion centers. Each CuII center exhibits distorted octahedral coordination provided by two pyridyl N atoms from two equivalent L2 ligands and four O atoms from two equivalent tta ligands. The chains interact through weak C—F⋯H—C contacts.
