Volume 62, Issue 1 pp. m80-m82

C-meso-(3,5,7,7,10,12,12,14-Octa­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-4,11-diene)nickel(II) bis­(thio­cyanate)

First published: 26 January 2006

Abstract

The title complex, (1RS,3SR,8SR,10RS-3,5,7,7,10,12,12,14-octa­methyl-1,4,8,11-tetraazacyclotetra­deca-4,11-diene-κ4N1,4,8,11)­nickel(II) bis­(thio­cyanate), [Ni(C18H36N4)](NCS)2, has a centrosymmetrical square-planar singlet ground state nickel(II) cation, with Ni—Namine = 1.940 (1) Å and Ni—Nimine = 1.921 (1) Å. The C-3 methyl substituent is axially oriented. The thio­cyanate N atom is hydrogen bonded to the NH group.

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