C-meso-(3,5,7,7,10,12,12,14-Octamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) bis(thiocyanate)
Abstract
The title complex, (1RS,3SR,8SR,10RS-3,5,7,7,10,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-κ4N1,4,8,11)nickel(II) bis(thiocyanate), [Ni(C18H36N4)](NCS)2, has a centrosymmetrical square-planar singlet ground state nickel(II) cation, with Ni—Namine = 1.940 (1) Å and Ni—Nimine = 1.921 (1) Å. The C-3 methyl substituent is axially oriented. The thiocyanate N atom is hydrogen bonded to the NH group.