Volume 61, Issue 12 pp. m2548-m2549

Poly[diaqua­(μ6-benzene-1,2,4,5-tetra­carboxyl­ato)(μ6-2,5-dicarboxy­benzene-1,4-dicarboxyl­ato)disamarium]

First published: 09 December 2005

Abstract

The title compound, [Sm2(C10H2O8)(C10H4O8)(H2O)2]n or [Sm2(btec)(H2btec)(H2O)2]n, was synthesized hydro­­thermally by the reaction of Sm2O3 with 1,2,4,5-ben­zene­tetra­carboxylic acid (H4btec). The Sm atom is coordinated by nine O atoms, three from H2btec2−, five from btec4− and one from a coordinated water mol­ecule. Sm—O distances range from 2.376 (3) to 2.558 (5) Å.

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