Volume 60, Issue 11 pp. m1695-m1696

Bis­(iso­thio­cyanato-κN)­bis­[8-(methoxy­carbonyl­methoxy)­quinoline-κN]copper(II)

Rui-Feng Song

Rui-Feng Song

Department of Chemistry and Chemical Engineering, University of Science and Technology of Suzhou, Suzhou 215009, People's Republic of China

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Yu-Hong Wang

Yu-Hong Wang

Department of Chemistry and Chemical Engineering, University of Science and Technology of Suzhou, Suzhou 215009, People's Republic of China

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Fan Jiang

Fan Jiang

Department of Chemistry and Chemical Engineering, University of Science and Technology of Suzhou, Suzhou 215009, People's Republic of China

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First published: 04 November 2004
Citations: 1
Yu-Hong Wang, e-mail: [email protected]

Abstract

In the title mononuclear complex, [Cu(NSC)2(C13H11NO3)2], the iso­thio­cyanate ions and 8-(methoxy­carbonyl­methoxy)­quinoline mol­ecules act as monodentate ligands. The ligand geometry about the Cu centre, which lies on a twofold rotation axis, can be described as square-planar or grossly distorted octahedral, formed by two N atoms of the iso­thio­cyanate ions, two quinoline N atoms and two methoxy O atoms of the 8-(methoxy­carbonyl­methoxy)­quinoline ligands. The N—Cu—N cis angles around the Cu atom vary from 88.38 (12) to 94.27 (15)° and the Cu—N bond distances are 1.950 (2) and 2.024 (2) Å.

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