Volume 60, Issue 5 pp. o886-o888

6,6′-Bis­(chloro­methyl)-2,2′-bi­pyridine

Leonard F. Lindoy

Leonard F. Lindoy

Centre for Heavy Metals Research, School of Chemistry, University of Sydney, New South Wales 2006, Australia

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John C. McMurtrie

John C. McMurtrie

Centre for Heavy Metals Research, School of Chemistry, University of Sydney, New South Wales 2006, Australia

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Jason R. Price

Jason R. Price

Centre for Heavy Metals Research, School of Chemistry, University of Sydney, New South Wales 2006, Australia

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First published: 14 May 2004
Citations: 1
John C. McMurtrie, e-mail: [email protected]

Abstract

In the crystalline state, the two pyridyl groups of the centrosymmetric title mol­ecule, C12H10Cl2N2, are coplanar, with the N atoms trans to each other and with the Cl atoms of the chloro­methyl groups protruding on opposite sides of the bipyridyl plane. In the crystal structure, the mol­ecules are arranged in discrete layers propagated by edge-to-face and offset face-to-face aryl–aryl interactions. The interlayer spaces are occupied by chloro­methyl groups.

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