Abstract
In the crystalline state, the two pyridyl groups of the centrosymmetric title molecule, C12H10Cl2N2, are coplanar, with the N atoms trans to each other and with the Cl atoms of the chloromethyl groups protruding on opposite sides of the bipyridyl plane. In the crystal structure, the molecules are arranged in discrete layers propagated by edge-to-face and offset face-to-face aryl–aryl interactions. The interlayer spaces are occupied by chloromethyl groups.