Abstract
The Ni atom in the title complex, [Ni(C7H7N4O)2], is octahedrally coordinated by two mono-deprotonated Schiff bases that are derived from the condensation of pyridine-2-carbaldehyde and semicarbazide; the Schiff bases act as meridional tridentate ligands, each of them coordinating the metal with the deprotonated amidate oxygen [Ni—O = 2.0909 (15) and 2.0959 (15) Å], imine nitrogen [Ni—N = 1.9892 (18) and 1.9822 (18) Å] and pyridine nitrogen [Ni—N = 2.100 (2) and 2.1317 (2) Å]. The dihedral angle formed by the mean planes of the bicyclic chelate systems of each of the ligands is equal to 87.69 (4)°. The crystal packing is stabilized by intermolecular hydrogen bonds involving N—H⋯O and C—H⋯O interactions.