Volume 60, Issue 4 pp. m460-m461

Poly­[[[(1,10-phenanthroline-κ2N,N′)­cobalt(II)]-μ3-5-hydroxy­isophthalato-κ4O,O′:O′′:O′′′] monohydrate]

Xin-Yi Cao

Xin-Yi Cao

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Jian Zhang

Jian Zhang

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Yao Kang

Yao Kang

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Jian-Kai Cheng

Jian-Kai Cheng

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Zhao-Ji Li

Zhao-Ji Li

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Xiao-Qin Wang

Xiao-Qin Wang

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Yuan-Gen Yao

Yuan-Gen Yao

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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First published: 09 October 2008
Citations: 1
Yuan-Gen Yao, e-mail: [email protected]

Abstract

The title compound, {[Co(C8H4O5)(C12H8N2)]·H2O}n, is isostructural with its manganese analog [Skakle, Foreman & Plater (2001). Acta Cryst. E57, m373–m375]. The asymmetric unit consists of one Co atom, one 1,10-phenanthroline ligand bound in a bidentate manner, one hydroxy­isophthalate ligand and one water mol­ecule. The Co coordination is completed by two further O atoms from two symmetry-related hydroxy­isophthalate ligands, giving a grossly distorted octahedral geometry.

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