Volume 58, Issue 11 pp. o1244-o1246

2-(2′,3′,4′,6′-Tetra-O-acetyl-β-d-gluco­pyran­osyl­thio)-4-pyridin-4-yl-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]­pyridine-3-carbo­nitrile

First published: 29 July 2004
Peter G. Jones, e-mail: [email protected]

Abstract

In the title compound, C30H33N3O9S, the glucoside moiety is attached to the pyridone via the S atom. The expected absolute configuration was confirmed. Dimensions at sulfur are S—C(pyridone) 1.780 (2), S—C(glucoside) 1.803 (2) Å, C—S—C 98.15 (11)°. There are three short H⋯O contacts (<2.5 Å) that determine the molecular packing.

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