Volume 58, Issue 8 pp. m432-m433

Bis­[μ-bis­(di­phenyl­phosphino)­methane-κ2P:P′]­bis­[(saccharinato-κN)­palladium(I)] di­chloro­methane solvate

William Henderson

William Henderson

Chemistry Department, University of Waikato, Private Bag 3105, Hamilton, New Zealand

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Brian K. Nicholson

Brian K. Nicholson

Chemistry Department, University of Waikato, Private Bag 3105, Hamilton, New Zealand

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Dong C. Chung

Dong C. Chung

Chemistry Department, University of Waikato, Private Bag 3105, Hamilton, New Zealand

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First published: 29 July 2004
Brian K. Nicholson, e-mail: [email protected]

Abstract

The dimeric palladium(I) saccharinate complex [Pd2(sac)2(dppm)2], has been characterized as its di­chloro­methane solvate, i.e. [Pd2(C7H4NO3S)2(C25H22P2)2]·CH2Cl2. The complex features a Pd—Pd bond bridged by two dppm ligands, with the saccharinate ligands N-bonded trans to the Pd—Pd bond.

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