Volume 58, Issue 8 pp. m381-m382

Di-μ-iodo-bis{[bis(trans-cinnam­aldehyde)­ethyl­enedi­imine-κ2N,N′]copper(I)}

First published: 29 July 2004
Citations: 1
Guido Kickelbick, e-mail: [email protected]

Abstract

The title complex, [Cu(μ-I)(ca2en)]2 [ca2en is N,N′-bis(trans-cinnam­aldehyde)­ethyl­enedi­imine, C20H20N2], has a dimeric structure where two copper(I) ions are doubly bridged by iodine substituents. The inversion center is located midway between the two Cu atoms. The ca2en acts as a bidentate ligand coordinating via two N atoms to the copper. The coordination geometry around the Cu atom is a distorted tetrahedron formed by two N atoms from a bidentate di­imine ligand and two iodine substituents. The distance between the two Cu atoms is 2.635 (2) Å. The ca2en ligand adopts a Z,Z configuration.

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.