Volume 58, Issue 3 pp. m86-m87

(N,N-Diethyl­di­thio­carbamato)[tris(p-methoxy­phenyl)­phosphine]­gold(I)

Soo Yei Ho

Soo Yei Ho

Department of Chemistry, National University of Singapore, Singapore 117543

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Edward R. T. Tiekink

Edward R. T. Tiekink

Department of Chemistry, National University of Singapore, Singapore 117543

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First published: 29 July 2004
Citations: 1
Edward R. T. Tiekink, e-mail: [email protected]

Abstract

Sulfur- and phospho­rus-donor atoms define an approximately linear geometry about the Au atom in the title compound, [Au(S2CNEt2){(p-MeO-C6H4)3P}]. The key geometric parameters are Au—S 2.3350 (8) Å, Au—P 2.2528 (7) Å and an S—Au—P angle of 169.80 (3)°. The deviation from linearity is ascribed to a close intramolecular Au⋯S contact of 3.0564 (8) Å.

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