Volume 57, Issue 8 pp. o814-o815

NS,NO-Di­phenyl­(thio­ox­amide)

Victor B. Rybakov

Victor B. Rybakov

Chemistry Department, Moscow State University, 119899 Moscow, Russia

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Eugene V. Babaev

Eugene V. Babaev

Chemistry Department, Moscow State University, 119899 Moscow, Russia

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Ylya V. Dlinnykh

Ylya V. Dlinnykh

Chemistry Department, Moscow State University, 119899 Moscow, Russia

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First published: 03 August 2004
Victor B. Rybakov, e-mail: [email protected]

Abstract

The mol­ecule of the title compound, PhNHC(=S)C(=O)NHPh or C14H12N2OS, consists of two planar fragments, one of which includes the central NHC(=S)C(=O)NH chain together with the Ph substituent on the C=O side; the second Ph ring, the one on the C=S side, all by itself, makes up the second planar fragment. Its plane is twisted about the N—C bond by 52.87 (9)° with respect to the plane of the first fragment. The C=S and C=O double bonds adopt the transoid conformation with the torsion angle S=C—C=O equal to −179.6 (2)°. The mol­ecules in the crystal are linked into centrosymmetric dimers due to the N—H⋯O hydrogen bond involving the thio­amide NH group.

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