Volume 57, Issue 8 pp. m338-m340

cis-Di­carbonyl­bis­[1,2-ethanediyl­bis­(di­phenyl­phosphine)-P,P′]­tungsten(0) benzene sesquisolvate

Alexander C. Filippou

Alexander C. Filippou

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Straße 1-2, D-10115 Berlin, Germany

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Athanassios I. Philippopoulos

Athanassios I. Philippopoulos

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Straße 1-2, D-10115 Berlin, Germany

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Burkhard Ziemer

Burkhard Ziemer

Institut für Chemie, Humboldt-Universität zu Berlin, Hessische Straße 1-2, D-10115 Berlin, Germany

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First published: 03 August 2004
Burkhard Ziemer, e-mail: [email protected]

Abstract

The title compound, cis-[W(CO)2(dppe)2] [dppe is 1,2-ethane­diyl­bis­(di­phenyl­phosphine), C26H24P2], was obtained as a by-product during the preparation of the di­nitro­gen complex trans-[W(CO)(N2)(dppe)2]. The crystal structure of the benzene sesquisolvate, i.e. cis-[W(C26H24P2)2(CO)2]·1.5C6H6, has been determined.

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