Volume 56, Issue 1 pp. 19-21

Bis(μ-succinato-O,O′:O′′,O′′′)bis[bis(2-amino-1,3-benzothiazole-N3)copper(II)]

Lesław Sieroń

Lesław Sieroń

Institute of General and Ecological Chemistry, Technical University of Łódź, Żwirki 36, 90-924 Łódź, Poland

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Maria Bukowska-Strzyżewska

Maria Bukowska-Strzyżewska

Institute of General and Ecological Chemistry, Technical University of Łódź, Żwirki 36, 90-924 Łódź, Poland

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First published: 01 July 2004
Maria Bukowska-Strzyżewska, e-mail: [email protected]

Abstract

In the title dimeric complex, [Cu2(C4H4O4)2(C7H6N2S)4], which possesses a centre of symmetry, the Cu atoms are enclosed in a 14-membered ring. They adopt a distorted square-bipyramidal (4+2) coordination. The four closest donor atoms are two N atoms of 2-amino­benzo­thiazole ligands and two O atoms of the succinate carboxylate groups. They form a square-planar cis arrangement, with an average Cu—N distance of 2.003 (3) Å and Cu—O distances of 1.949 (3) and 1.965 (3) Å. Two longer Cu—O bonds of 2.709 (3) and 2.613 (3) Å involving the remaining O atoms of the carboxylate groups complete the sixfold coordination of the Cu atoms. The H atoms of each amino group of the 2-amino­benzo­thiazole molecules form intra- and inter­molecular N—H⋯O hydrogen bonds. A nearly perpendicular inter­molecular C—H⋯Cg interaction (Cg is the centroid of the imidazole ring) is observed. The intramolecular Cu⋯Cu distance is 6.384 (2) Å.

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