Volume 59, Issue 12 pp. o712-o714

ap-9-(o-Methyl­phenyl)-9-fluorenol, a structure exhibiting several aryl-H⋯π(arene) intermolecular interactions

First published: 08 June 2004
Paul D. Robinson, e-mail: [email protected]

Abstract

The title compound, C20H16O, (I), which crystallized exclusively as its ap rotamer, exhibits several intermolecular aryl-H⋯π(arene) interactions, resulting in planar molecular arrays in which each mol­ecule interacts with six adjacent mol­ecules. Surprisingly, there were no O—H⋯O—H or O—H⋯π(arene) interactions within hydrogen-bonding distances. Crystalline (I) melted sharply without molecular decomposition (NMR), but the cooled melt recrystallized only after several hours.

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