Volume 57, Issue 4 pp. 497-498

(3R,4aS,5R)-3-Hydro­xy-5-isopropenyl-3,8-di­methyl-4,4a,5,6-tetra­hydro-2(3H)-naphthalenone

Dianne D. Ellis

Dianne D. Ellis

Bijvoet Centre for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Search for more papers by this author
Anthony L. Spek

Anthony L. Spek

Bijvoet Centre for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Search for more papers by this author
First published: 23 June 2004
Citations: 1
Dianne D. Ellis, e-mail: [email protected]

Abstract

In the crystal structure of C15H20O2, mol­ecules are associated by intermolecular hydrogen bonds between the hydroxy function and a keto group [O⃛O 2.770 (2) Å], forming chains along the [100] direction in the crystal. Both six-membered rings in the decalin unit adopt envelope conformations; one section of the mol­ecule, encompassing the extended conjugation of a C=C double bond with an enone functionality [C=C—C=O = 175.6 (2)° and C=C—C=C = 176.6 (2)°], is flat, whilst the rest of the mol­ecule is folded relative to the constrained part. The stereochemistry was determined from the R-(–)-carvone starting material.

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.