Volume 57, Issue 4 pp. 473-475

3′,4′-Bis(4-chloro­phenyl)­spiro­[chroman-3,5′(4′H)-isoxazol]-4-one

First published: 23 June 2004
Citations: 1
S. Parthasarathy, e-mail: [email protected]

Abstract

The title compound, C23H15Cl2NO3, crystallizes with two independent mol­ecules in the asymmetric unit. The chroman­one moiety consists of a benzene ring fused with a six-membered heterocyclic ring which adopts a sofa conformation. The five-membered spiro­isoxazoline ring is in an envelope conformation. The p-chloro­phenyl rings bridged by the five-membered ring are nearly perpendicular to each other. The chromanone moiety of one mol­ecule packs into the cavity formed by the p-chloro­phenyl rings of a second mol­ecule through the formation of C—H⃛π interactions. The structure is stabilized by weak C—H⃛O, C—H⃛Cl and C—H⃛π interactions.

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